Covalently Bonded Antifoam Compositions for Detergent Stability

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Solution Overview

Problem

Existing anti-foam compositions with low viscosity silicones are ineffective due to separation caused by detergent ingredients, leading to compromised antifoaming performance in cleaning and treatment compositions.

Innovation Solution

Development of covalently bonded antifoam compositions with organopolysiloxanes, non-linear organosilicone resins, and hydrophobic fillers, which are heat-treated and sheared to improve antifoaming properties and stability, allowing for effective antifoaming performance even in the presence of detergent ingredients.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If low viscosity silicones are employed in anti-foam compositions to avoid emulsification, then ease of manufacture is improved, but antifoaming effectiveness deteriorates due to separation caused by detergent ingredients

Engineering Contradiction:
Improveease of manufactureVSAvoidantifoaming effectiveness
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent employs a composite anti-foam composition comprising high viscosity silicone (providing structural integrity and resistance to separation), low viscosity silicone (providing rapid antifoam action), and emulsifier (ensuring compatibility with detergent ingredients). This composite approach combines the advantages of both viscosity types while mitigating their individual disadvantages, achieving both ease of manufacture and reliable antifoaming effectiveness.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces an emulsifier as an intermediary substance that mediates between the silicone components and detergent ingredients. The emulsifier prevents separation by forming stable emulsions, allowing the anti-foam composition to remain effective in the presence of solvents, polymers, and perfumes that would otherwise cause component separation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If high viscosity silicones are used in anti-foam compositions, then antifoaming effectiveness is improved, but device complexity increases due to required emulsification step

Engineering Contradiction:
Improveantifoaming effectivenessVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges multiple functions into a single anti-foam composition formulation. By combining high viscosity silicone, low viscosity silicone, and emulsifier into one integrated composition, the patent eliminates the need for separate emulsification steps that would otherwise be required when using high viscosity silicones alone. This merged approach maintains antifoaming effectiveness while simplifying the manufacturing process.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent performs preliminary action by pre-formulating the anti-foam composition with all necessary components (high viscosity silicone, low viscosity silicone, and emulsifier) mixed and stabilized before incorporation into the detergent product. This preliminary preparation ensures that no additional emulsification steps are needed during final product manufacturing, reducing process complexity while maintaining effectiveness.

Inventive Principle:
Principle #10Preliminary action

3Ease of operation

If low viscosity silicones are used to simplify manufacturing, then ease of operation is improved, but antifoaming performance deteriorates due to component separation by detergent ingredients

Engineering Contradiction:
Improveease of operationVSAvoidantifoaming performance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent creates a composite anti-foam system that combines low viscosity silicone (providing ease of operation and rapid action) with high viscosity silicone and emulsifier (providing stability and preventing separation). This composite structure allows the composition to be easily incorporated into detergent products while maintaining reliable antifoaming performance despite the presence of solvents, polymers, and perfumes.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The emulsifier serves as an intermediary that protects the silicone components from separation by detergent ingredients. It mediates the interaction between the hydrophobic silicone and the aqueous detergent environment, ensuring that the low viscosity silicone remains effectively dispersed and functional throughout the product shelf life and during use.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting antifoam compositions maintain effectiveness despite the presence of detergent ingredients, providing superior antifoaming properties and stability in cleaning and treatment products.

Implementation Method 1

Si-O-Si groups are formed from the reaction of Si-OH and/or Si-OR groups on one antifoam component with another antifoam component's Si-OH and/or Si-OR groups

Methodology Applied
Scientific EffectCondensation reaction: Chemical Bonding

Implementation Method 2

the antifoam further comprises a hydrophobic filler

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

such antifoam components react such that Si-O-Si groups are formed

Methodology Applied
Scientific EffectThermal activation: Heating

Data Source

PatentEP3707231B1Anti-foam compositions
Publication Date: 2021.12.01 PROCTER & GAMBLE CO
  • EP3707231B1 patent drawing
  • EP3707231B1 patent drawing
  • EP3707231B1 patent drawing

AI summary

The present application relates to anti-foam compositions and methods of making and using such compositions as well as consumer products that comprise such compositions and the use of same. Such anti-foam compositions have low viscosities yet are effective antifoamers.