Antifouling Sheet With Gradient Photocatalyst Layer

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Solution Overview

Problem

Existing antistaining sheets face challenges in maintaining effective antistaining properties over a long period without forming a thick antistaining layer, as the self-collapse of the antistaining layer proceeds rapidly, leading to premature degradation and inadequate stain removal, especially with inorganic stains like sand and metal rust.

Innovation Solution

The antistaining sheet features a multi-layer structure with a surface layer having a higher photocatalyst content and faster thermoplastic resin decomposition than the inner layer, ensuring strong self-collapsing properties on the surface while maintaining antistaining performance over time without excessive thickness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the self-collapsing property of the antistaining layer is enhanced to achieve rapid antistaining effect, then the antistaining property is improved, but the layer collapses too quickly and loses its function

Engineering Contradiction:
Improveantistaining effect development speedVSAvoidservice life of antistaining layer
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The antistaining layer is divided into multiple sub-layers with different photocatalyst contents. The surface layer has higher photocatalyst content for rapid initial antistaining effect, while the lower layer has lower photocatalyst content for sustained long-term performance, resolving the contradiction between quick action and durability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the antistaining layer are given different properties: the surface layer is designed with high photocatalyst concentration for aggressive stain decomposition, while the base layer maintains lower concentration for stability and extended service life, allowing each region to perform its specific function optimally

Inventive Principle:
Principle #3Local quality

2Duration of action of stationary object

If the antistaining layer is made thick to ensure long-term performance, then the service life is extended, but manufacturing complexity and cost increase

Engineering Contradiction:
Improveservice life of antistaining layerVSAvoidmanufacturing complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

Instead of using a single thick layer, the system segments the functionality into multiple thinner sub-layers with distinct photocatalyst concentrations. This achieves the same total photocatalyst content and service life as a thick layer but simplifies manufacturing processes and reduces material costs

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the parameter distribution of photocatalyst content across the layer thickness rather than uniformly increasing overall thickness. By optimizing the concentration gradient from surface to base, the system achieves extended service life through parameter optimization rather than increased dimensional complexity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design enables rapid development of antistaining effects at the start of use and sustained performance over the product's lifetime, preventing premature layer collapse and effectively removing organic stains while managing inorganic stains through controlled layer degradation.

Implementation Method 1

the photocatalyst receives photoenergy when the antistaining layer is irradiated with light such as sunlight, exposes the photocatalyst itself onto the surface of the antistaining layer while decomposing the thermoplastic resin present as surrounding the photocatalyst

Methodology Applied
Scientific EffectPhotocatalysis: Photo-oxidation

Implementation Method 2

decomposing the thermoplastic resin that is decomposed by the redox action of the photocatalyst

Methodology Applied
Scientific EffectRedox reaction: Redox Reactions

Implementation Method 3

the photocatalytic effect increases the hydrophilicity of the sheet surface and consequently the stains are cleaned with rain water or the like

Methodology Applied
Scientific EffectPhotocatalytic effect: Photo-oxidation

Data Source

PatentEP2460655B1Antifouling sheet
Publication Date: 2014.08.20 KANBO PRAS CORP
  • EP2460655B1 patent drawingFigure 1
  • EP2460655B1 patent drawingFigure 2
  • EP2460655B1 patent drawingFigure 3

AI summary

Disclosed is an antistaining sheet including a base material sheet and an antistaining layer formed on the base material sheet. The antistaining layer includes a photocatalyst and a thermoplastic resin to be decomposed by the photocatalyst, and thus has a self-collapsing property. The antistaining layer is stronger in self-collapsing property in the surface portion thereof than in the interior portion.