Antimicrobial Blends for Water-Insoluble Biocide Delivery

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Solution Overview

Problem

Existing antimicrobial compositions for personal care products face challenges in delivering water-insoluble biocides at high concentrations due to limited aqueous solubility, which affects their preservative activity against bacteria, fungi, and mold spores.

Innovation Solution

A blend of 1,2-diol (such as 1,2-pentanediol, 1,2-hexanediol, or 1,2-octanediol) and phenoxyethanol, combined with a co-biocide like sorbic acid or iodopropynyl butyl carbamate, at specific weight ratios and HLB values, to enhance the solubility and efficacy of water-insoluble biocides in aqueous personal care systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If water-insoluble biocides are used at high concentrations, then antimicrobial activity is improved, but aqueous solubility deteriorates

Engineering Contradiction:
Improveantimicrobial activityVSAvoidaqueous solubility
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent uses 1,2-diol as an intermediary substance to bridge the incompatibility between water-insoluble biocides and aqueous systems. The 1,2-diol forms a co-solvent system with phenoxyethanol that enables high concentrations of water-insoluble biocides to be delivered in aqueous personal care products while maintaining solubility and antimicrobial activity

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If preservative concentration is increased to control microbial growth, then antimicrobial efficacy is improved, but skin safety deteriorates

Engineering Contradiction:
Improvemicrobial growth controlVSAvoidskin toxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the preservative system by using 1,2-diol in specific concentration ranges (0.5-5%) combined with phenoxyethanol, which allows achieving effective microbial control at lower overall preservative concentrations, thereby reducing skin toxicity while maintaining efficacy

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively reduces microbial growth in personal care products, maintaining antimicrobial activity against a broad spectrum of microorganisms, including bacteria, yeast, and mold spores, even at high concentrations, thereby extending product shelf life and safety.

Implementation Method 1

A blend of 1,2-diol (such as 1,2-pentanediol, 1,2-hexanediol, or 1,2-octanediol) and phenoxyethanol, combined with a co-biocide like sorbic acid or iodopropynyl butyl carbamate, at specific weight ratios and HLB values, to enhance the solubility and efficacy of water-insoluble biocides in aqueous personal care systems

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS7935732B2Antimicrobial compositions
Publication Date: 2011.05.03 ISP INVESTMENTS LLC

AI summary

What is described herein are antimicrobial compositions which are defined blends of a 1,2-diol and phenoxyethanol which show broad activity against bacteria, fungi and mold spores. This activity is potentiated by the addition thereto of small amounts of a co-biocide for which the blend acts as a delivery system for the otherwise water-insoluble co-biocide.