Antimicrobial Polymer Packaging for Shelf-Life Extension

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Solution Overview

Problem

Current methods for preserving perishable goods like baked goods are ineffective in extending shelf-life without causing undesirable side effects, as high concentrations of antimicrobials can affect taste, odor, and transparency of packaging materials, and existing solutions require high additive levels that may migrate into food, leading to turbidity and other issues.

Innovation Solution

A polymer composition comprising a thermoplastic polymer matrix with low concentrations of zinc pyrithione and silver, combined with low levels of zeolite, which synergistically extends the shelf-life of perishable goods while maintaining transparency and avoiding taste and odor issues, even when not in direct contact with the goods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high concentrations of antimicrobials are used to extend shelf-life, then microbial protection is improved, but taste and odor are adversely affected

Engineering Contradiction:
Improvemicrobial protectionVSAvoidtaste and odor
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent combines zinc pyrithione and silver in a composite polymer packaging material to achieve synergistic antimicrobial effects. This composite approach allows lower individual concentrations of each antimicrobial agent while maintaining effective microbial protection, thereby avoiding the taste and odor issues associated with high concentrations of single antimicrobials.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the concentration parameters of zinc pyrithione and silver within specific ranges (zinc pyrithione: 50-6000 ppm, silver: 50-6000 ppm) to achieve effective antimicrobial activity while minimizing adverse effects on taste and odor. This parameter optimization resolves the contradiction between sufficient microbial protection and maintaining sensory quality.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If high amounts of zeolite are used as antimicrobial additive, then microbial growth prevention is improved, but transparency of packaging is worsened

Engineering Contradiction:
Improvemicrobial growth preventionVSAvoidtransparency
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent creates a composite material system combining zinc pyrithione, silver, and zeolite in optimized proportions. This composite approach allows the use of lower zeolite content (100-6000 ppm) while maintaining effective microbial protection through the synergistic action of all components, thereby preserving packaging transparency.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the zeolite concentration parameter within the range of 100-6000 ppm, which is significantly lower than conventional approaches requiring at least 2.5% zeolite. This parameter reduction minimizes light diffusion and maintains packaging transparency while still achieving effective microbial protection through the combined antimicrobial system.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If high contents of preservatives are used to extend shelf-life, then microbial protection is improved, but migration into food is increased

Engineering Contradiction:
Improvemicrobial protectionVSAvoidpreservative migration
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent employs a composite antimicrobial system where zinc pyrithione and silver work synergistically, allowing each component to be used at lower concentrations (50-6000 ppm each) rather than relying on high amounts of a single preservative. This reduces the total migration burden into food while maintaining effective microbial protection.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The polymer matrix acts as an intermediary carrier that controls the release and migration of antimicrobial agents into food. The optimized low concentrations of zinc pyrithione and silver in the polymer matrix provide sustained protection while minimizing direct migration into the food product.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination of zinc pyrithione, silver, and zeolite significantly increases the shelf-life of perishable goods by at least 50% without affecting taste or odor, while maintaining transparency and reducing microbial contamination, outperforming comparable unprotected goods.

Implementation Method 1

50 to 6000 ppm, related to the polymer composition, of zinc pyrithione (component B); 50 to 6000 ppm, related to the polymer composition, of silver... significantly increased shelf-life of foodstuff

Methodology Applied
Scientific EffectAntimicrobial action:

Implementation Method 2

100 to 6000 ppm, related to the polymer composition, of a zeolite (component D)... The present invention allows at least 50% longer shelf-life of perishable goods

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP3891079B1Antimicrobial polymer composition for shelf-life extension
Publication Date: 2023.03.15 CLARIANT INT LTD

AI summary

Polymer composition are provided comprising a thermoplastic polymer matrix, 50 to 6000 ppm of zinc pyrithione, 50 to 6000 ppm of silver, 100 to 6000 ppm of a zeolite,and optionally 0 to 5% by weight of one or more polymer additives. The invention also relates to a masterbatch and a method for preparing such polymer composition. The present invention further relates to a food packaging comprising or consisting of such polymer composition and to the use thereof for increasing shelf-life of foodstuff such as baked goods.