Antimony LDS Resin for Plated Flame-Retardant Electronics

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Solution Overview

Problem

The challenge is to develop a resin composition for laser direct structuring that achieves both high platability and flame retardancy, particularly when using halogen-containing flame retarders, as existing methods fail to form a plating layer effectively with such additives.

Innovation Solution

A resin composition combining a halogen-containing flame retarder with an antimony-containing laser direct structuring additive, along with an inorganic filler like glass fiber, achieves high platability and flame retardancy, with the antimony content ensuring effective plating and mechanical strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a halogen-containing flame retarder is blended to a thermoplastic resin to improve flame retardancy, then flame retardant properties are improved, but platability is deteriorated (plating cannot be formed)

Engineering Contradiction:
Improveflame retardancyVSAvoidplatability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters by introducing an antimony-containing laser direct structuring additive with specific characteristics (particle size, content ratio) that modifies the surface properties during laser irradiation, enabling plating formation despite the presence of halogen-containing flame retarder in the bulk resin

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining thermoplastic resin, halogen-containing flame retarder, and antimony-containing laser direct structuring additive, where the synergistic interaction between components allows simultaneous achievement of flame retardancy and platability

Inventive Principle:
Principle #40Composite materials

2Reliability

If an antimony-containing flame retarder auxiliary is added to achieve flame retardancy, then flame retardant properties are improved, but platability is further deteriorated

Engineering Contradiction:
Improveflame retardancyVSAvoidplatability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent precisely controls the content ratio of antimony-containing flame retarder auxiliary to be 0.5 parts by weight or less per 100 parts by weight of thermoplastic resin, and optimizes the content ratio of antimony-containing laser direct structuring additive to 1 to 30 parts by weight, creating a parameter window where both flame retardancy and platability are achieved

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition enables the formation of a plated resin molding with excellent flame retardant properties, rated as V-0 in the UL 94 test, while maintaining high platability and mechanical strength, suitable for manufacturing antenna-equipped portable electronic device parts.

Implementation Method 1

LDS is a technique for forming a plating layer, by irradiating laser on the surface of a resin molding that contains a LDS additive, to thereby activate only the irradiated area

Methodology Applied
Scientific EffectLaser irradiation activation: Laser

Implementation Method 2

combined use of the halogen-containing flame retarder and an antimony-containing LDS additive successfully achieved a high level of flame retardant

Methodology Applied
Scientific EffectFlame retardancy:

Data Source

PatentUS10815377B2Resin composition, resin molding, method for manufacturing plated resin molding, and method for manufacturing antenna-equipped portable electronic device part
Publication Date: 2020.10.27 GLOBAL POLYACETAL CO LTD
  • US10815377B2 patent drawing

AI summary

Provided is a resin molding that uses a resin composition capable of achieving high platability, while being imparted flame retardant by the halogen-containing flame retarder, a method for manufacturing a plated resin molding, and a method for manufacturing an antenna-equipped portable electronic device part. The resin composition comprises 100 parts by weight of a thermoplastic resin; 5 to 100 parts by weight of a halogen-containing flame retarder; and, 1 to 30 parts by weight of a laser direct structuring additive, wherein the laser direct structuring additive contains antimony, and; a content of an antimony-containing flame retarder auxiliary is 0.5 parts by weight or less per 100 parts by weight of the thermoplastic resin.