Antioxidant Particles Stabilize Emulsion Interfaces

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Solution Overview

Problem

Emulsions, such as oil-in-water emulsions, are thermodynamically unstable and prone to lipid oxidation, which affects nutritional and sensory quality, and existing stabilizers like surfactants and proteins may not adequately prevent oxidation, especially when lipids contain unsaturated bonds.

Innovation Solution

The use of particles prepared from biological materials, such as high melting point lipids or plant extracts, which are capable of locating at the interface between immiscible liquids, providing a mechanical barrier and incorporating antioxidants to prevent lipid oxidation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If conventional surfactants or proteins are used to stabilize emulsions, then emulsion stability is improved, but lipid oxidation resistance is insufficient

Engineering Contradiction:
Improveemulsion stabilityVSAvoidlipid oxidation
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent uses composite particles comprising both stabilizing agents (surfactants or proteins) and antioxidants (such as tocopherols, ascorbates, or phenolic compounds). This composite structure allows the particles to simultaneously provide emulsion stabilization through interfacial adsorption and lipid oxidation protection through antioxidant activity, resolving the contradiction between emulsion stability and oxidation resistance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention merges the functions of emulsion stabilization and oxidation protection into a single particle system. By combining stabilizing agents and antioxidants within the same particle structure, the system performs dual functions: stabilizing the emulsion interface and preventing lipid oxidation, thereby eliminating the need for separate additives and resolving the functional gap in conventional systems.

Inventive Principle:
Principle #5Merging (Combining)

2Reliability

If particles from biological materials are used, then oxidative stability is enhanced, but emulsion formation complexity increases

Engineering Contradiction:
Improveoxidative stabilityVSAvoidemulsion formation process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs particles with multi-functional properties that can simultaneously stabilize emulsions and provide oxidation protection. These universal particles eliminate the need for multiple separate additives and simplify the overall formulation process, counteracting the perceived complexity by reducing the number of components and steps required.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The invention optimizes particle parameters such as size distribution, surface charge, and hydrophobicity to enhance both emulsion stability and oxidation resistance. By carefully controlling these parameters, the system achieves high oxidative stability while maintaining relatively simple emulsion formation processes through optimized particle characteristics rather than complex procedural steps.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The particles effectively stabilize emulsions by preventing lipid oxidation, enhancing oxidative stability and extending the shelf-life of food and pharmaceutical products, even when compared to conventional emulsifiers.

Implementation Method 1

particles are capable of locating to, or are located at, an interface when combined with two or more immiscible liquids

Methodology Applied
Scientific EffectInterface adsorption: Adsorption

Implementation Method 2

Pickering particles may also be used to stabilize emulsions. It is believed that the particles anchor in the interface and provide a mechanical (steric) barrier protecting the lipid droplets against coalescence.

Methodology Applied
Scientific EffectPickering stabilization:

Implementation Method 3

incorporating antioxidants to prevent lipid oxidation

Methodology Applied
Scientific EffectAntioxidant action: Oxidation

Data Source

PatentUS20210283563A1Emulsion comprising antioxidant particles
Publication Date: 2021.09.16 GIVAUDAN FRANCE NATURALS SAS
  • US20210283563A1 patent drawing
  • US20210283563A1 patent drawing
  • US20210283563A1 patent drawing

AI summary

The present invention relates to compositions comprising particles prepared from one or more biological materials and/or animal lipids and/or plant lipids that are capable of locating to an interface when combined with two or more immiscible liquids. Emulsions comprising the compositions comprising particles, wherein the emulsion has an internal phase dispersed in a continuous external phase and the particles are located at the interface of the external and the internal phase, methods of preparing such compositions and emulsions, the use of such compositions and emulsions and products containing the compositions and emulsions are also described.