Antireflection Film Adhesion Layer for Abrasion Resistance

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Solution Overview

Problem

Existing antireflection films with fine uneven structures or metal-dielectric laminates lack durability and abrasion resistance, making them unsuitable for applications where mechanical strength is required, such as camera lenses.

Innovation Solution

An antireflection film with a silver-containing metal layer, a multilayer interlayer of alternating high and low refractive index layers, and a dielectric layer including silicon-containing oxide, magnesium fluoride, and an adhesion layer to enhance adhesiveness and durability, laminated in a specific order on a substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If an antireflection film with a fine uneven structure or porous structure is used to achieve ultra-low reflectivity, then the antireflection performance is improved, but the mechanical strength and abrasion resistance deteriorate

Engineering Contradiction:
Improvelight loss due to reflectionVSAvoidmechanical strength and abrasion resistance
Core Design Contradiction:
Loss of energyVSStrength

Solution Approach 1:

The patent uses a composite structure combining a metal layer containing silver (50-90 atomic %) with dielectric layers having different refractive indices. This composite material approach achieves ultra-low reflectivity (0.2% or less) across the visible spectrum while maintaining mechanical strength and abrasion resistance, as the metal-dielectric laminate provides both optical functionality and structural durability without requiring fragile fine uneven or porous structures.

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If a metal layer containing silver is provided between dielectric layers to achieve lower reflectivity, then the antireflection performance is improved, but the abrasion resistance is insufficient

Engineering Contradiction:
ImprovereflectivityVSAvoidabrasion resistance
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent employs a multi-layer composite structure where a metal layer containing silver (50-90 atomic %) is sandwiched between dielectric layers with different refractive indices. This composite configuration achieves ultra-low reflectivity (0.2% or less) while the outer dielectric layers provide protective functionality that improves abrasion resistance compared to exposed metal surfaces.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The dielectric layers act as protective thin film shells covering the metal layer, providing mechanical protection and abrasion resistance while maintaining the optical antireflection properties. The layered film structure allows the metal layer to be protected from direct exposure to external forces.

Inventive Principle:
Principle #30Flexible shells and thin films

3Loss of energy

If a fine uneven structure or porous structure is used on the uppermost layer to achieve low reflectivity, then the optical performance is improved, but the film becomes very weak to external force such as wiping

Engineering Contradiction:
ImprovereflectivityVSAvoidsensitivity to external force
Core Design Contradiction:
Loss of energyVSObject-affected harmful factors

Solution Approach 1:

The patent replaces fragile fine uneven or porous structures with a robust metal-dielectric laminate composite. The metal layer containing silver (50-90 atomic %) combined with dielectric layers provides both ultra-low reflectivity (0.2% or less) and high resistance to external forces such as wiping, eliminating the weakness of surface-structured films.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention avoids using fragile structures that are sensitive to external forces by employing a durable metal-dielectric laminate that can withstand mechanical stress, wiping, and handling, making it suitable for practical applications where the film must endure regular use.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides high durability and improved abrasion resistance while maintaining excellent antireflection performance, suitable for applications where mechanical strength is essential, such as camera lenses.

Implementation Method 1

an adhesion layer provided between the silicon-containing oxide layer and the magnesium fluoride layer and configured to increase adhesiveness between the silicon-containing oxide layer and the magnesium fluoride layer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

the interlayer is a multilayer film having at least two layers in which a layer of high refractive index having a relatively high refractive index and a layer of low refractive index having a relatively low refractive index are alternately laminated

Methodology Applied
Scientific EffectOptical interference: Interference

Implementation Method 3

a layer of high refractive index having a relatively high refractive index and a layer of low refractive index having a relatively low refractive index

Methodology Applied
Scientific EffectRefraction: Refraction

Data Source

PatentUS11422290B2Antireflection film, optical element, and optical system
Publication Date: 2022.08.23 FUJIFILM CORP
  • US11422290B2 patent drawing
  • US11422290B2 patent drawing
  • US11422290B2 patent drawing

AI summary

An antireflection film is provided on a substrate and includes an interlayer, a silver-containing metal layer containing silver, and a dielectric layer, which are laminated in this order on a side of a substrate, in which the interlayer is a multilayer film having at least two layers in which a layer of high refractive index having a relatively high refractive index and a layer of lower refractive index having a relatively low refractive index are alternately laminated, the dielectric layer has a surface exposed to air, and the dielectric layer is a multilayer film including a silicon-containing oxide layer, a magnesium fluoride layer, and an adhesion layer provided between the silicon-containing oxide layer and the magnesium fluoride layer and configured to increase adhesiveness between the silicon-containing oxide layer and the magnesium fluoride layer.