Antistatic Microcontact Printing Stamp for Fine Patterns

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Solution Overview

Problem

Silicone rubber compositions used in microcontact printing are prone to electrostatic charging, leading to contamination with nonfunctional low-molecular-weight siloxane compounds, which affects the conductivity of transferred ink and the accuracy of fine feature patterns, and existing antistatic agents fail to provide satisfactory results at elevated temperatures or in reversing fine-feature patterns.

Innovation Solution

Incorporating an ionic conducting antistatic agent into the addition reaction cure silicone rubber composition, which includes organopolysiloxane, organohydrogenpolysiloxane, an addition reaction catalyst, and a reinforcing resin, to create an antistatic microcontact printing stamp that remains electrically insulating and effective at maintaining pattern accuracy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If polyether antistatic agents are used in silicone rubber composition, then antistatic effect is achieved, but they decompose at elevated temperature and fail to maintain antistatic properties

Engineering Contradiction:
Improveelectrostatic chargeVSAvoidantistatic effect at elevated temperature
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical nature of the antistatic agent from polyether (which decomposes at high temperature) to an ionic conducting compound that maintains stability at elevated temperatures while providing continuous antistatic effect through ion conduction mechanism

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the decomposable polyether antistatic agent with a stable ionic conducting compound that does not decompose, effectively creating a permanent rather than temporary antistatic solution

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-generated harmful factors

If carbon black antistatic agents are used in silicone rubber composition, then antistatic effect is achieved, but reversal of fine-feature pattern becomes impossible

Engineering Contradiction:
Improveelectrostatic chargeVSAvoidfine-feature pattern reversal
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

The patent uses ionic conducting compounds that can be distributed at molecular level throughout the silicone rubber matrix, providing uniform antistatic properties without creating large particulate structures that would interfere with fine-feature pattern reversal

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent creates a composite silicone rubber material incorporating ionic conducting compounds that combine the electrical insulating properties of silicone rubber with the antistatic properties of ionic conductors, achieving both fine-feature pattern capability and antistatic effect

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If silicone rubber composition contains nonfunctional low-molecular-weight siloxane compounds, then ease of working is improved, but ink conductivity decreases due to siloxane contamination

Engineering Contradiction:
Improveease of workingVSAvoidink electrical conductivity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent introduces ionic conducting compounds as intermediary substances that counteract the harmful effect of siloxane contamination by providing alternative conduction pathways, allowing the silicone rubber to maintain both processability and ink conductivity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The antistatic microcontact printing stamp achieves improved electrical insulation and reduced contamination, maintaining pattern accuracy and preventing foreign matter adsorption, with the ionic conducting agent ensuring effective antistatic properties even at elevated temperatures.

Implementation Method 1

an ionic conducting antistatic agent in an addition reaction cure silicone rubber composition

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

addition reaction cure silicone rubber composition comprising an organopolysiloxane (A) and an organohydrogenpolysiloxane (B) as a curing agent

Methodology Applied
Scientific EffectAddition reaction: Chemical Bonding

Data Source

PatentEP2309328B1Microcontact printing stamps
Publication Date: 2015.07.22 SHIN ETSU CHEMICAL CO LTD

AI summary

An antistatic microcontact printing stamp is formed by curing a silicone rubber composition on a master. An addition reaction cure silicone rubber composition is used comprising (A) an organopolysiloxane containing at least two aliphatic unsaturated monovalent hydrocarbon groups, (B) an organohydrogenpolysiloxane containing at least two SiH groups, (C) an addition reaction catalyst, (D) a reinforcing resin, and (E) ionic-conducting antistatic agent such as a lithium salt.