Alkyl Polyglycoside Oil Separation in Corn Ethanol Stillage

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Solution Overview

Problem

Current corn to ethanol processing systems face inefficiencies in separating corn oil from stillage, resulting in reduced oil yield and recovery, particularly in the dry milling process where separation techniques like centrifugation and heat treatment do not effectively extract corn oil from the syrup stream.

Innovation Solution

The method involves adding an oil separation aid, specifically alkyl polyglycosides (APGs) to the process stream mixture in corn to ethanol processing, which includes whole stillage, thin stillage, evaporator streams, or feed water, to enhance oil separation through conventional techniques like centrifuging or solvent extraction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional separation techniques (centrifugation, heat treatment) are used to separate corn oil from stillage, then the process is simple and already in place, but the oil yield and recovery are reduced

Engineering Contradiction:
Improveoil yieldVSAvoidoil loss in syrup stream
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

Alkyl polyglycosides (APGs) are introduced as intermediary substances that mediate between the oil and water phases in stillage. These surfactants reduce interfacial tension and facilitate oil droplet coalescence, enabling more effective separation through existing centrifugation equipment without requiring new machinery or complex process changes.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the chemical parameters of the stillage system by adding APGs, which alter the interfacial properties between oil and water phases. This parameter change enables oil droplets to coalesce more effectively, increasing the oil phase separation efficiency and recovery yield through conventional separation equipment.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If heat treatment and centrifugation are applied to separate corn oil, then the process uses existing equipment, but the separation effectiveness is insufficient

Engineering Contradiction:
Improveoil separation efficiencyVSAvoidseparation effectiveness
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

APGs serve as chemical intermediaries that enhance the effectiveness of mechanical separation processes. By adding these surfactants, the separation reliability is improved as they promote oil droplet coalescence and phase separation, making the existing heat treatment and centrifugation processes more effective at extracting corn oil from the syrup stream.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Quantity of substance

If no oil separation aid is added, then the process is simple and cost-effective, but corn oil remains trapped in the syrup stream

Engineering Contradiction:
Improvecorn oil recoveryVSAvoidprocess complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The addition of APGs as intermediary substances provides a simple yet effective method to increase corn oil recovery. This approach maintains process simplicity while significantly improving oil extraction efficiency, as the APGs facilitate oil separation through their surfactant properties without requiring complex equipment or multi-step procedures.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of APGs significantly improves corn oil recovery by facilitating effective separation of oil from solids and water, increasing oil yield and making it suitable for industrial uses such as biodiesel, with optimal concentrations between 1-5000 ppm in the process stream.

Implementation Method 1

adding to the process stream mixture an oil separation aid comprising an alkyl polyglycoside (APG) or mixtures of APGs

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

The remaining mash is referred to as whole stillage. This whole stillage is then subjected to centrifuging or other separation techniques to result in a thin stillage and a wet cake.

Methodology Applied
Scientific EffectCentrifugal separation: Centrifugal Separation

Data Source

PatentUS9714398B2Method for improving corn oil extraction using alkyl polyglycosides
Publication Date: 2017.07.25 BL TECHNOLOGY INC

AI summary

Methods are provided for recovering oil from a process stream mixture in a corn to ethanol process. The method comprises adding an oil separation aid to the process stream wherein the oil separation aid is an alkyl polyglycoside (APG).