APHO Moisture-Repelling Films for High-Voltage Front-End FET Contacts

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Solution Overview

Problem

Integrated circuit (IC) structures operating at high frequencies and high power suffer from moisture ingress, leading to electrically shorted circuits due to moisture diffusion into semiconductor substrates, particularly at high temperatures and voltages, which compromises performance and increases losses.

Innovation Solution

The implementation of an Aminated-Polyhydroxy organic (APHO) film with specific chemical and physical properties, such as a thickness of 1 to 2 microns and a dielectric constant less than 2.1, is used to cover contacts on semiconductor substrates, providing moisture repelling properties and protecting against shorts, allowing high voltage applications while facilitating high-frequency signal propagation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional materials are used in high-power IC structures, then manufacturing is simpler, but moisture ingress causes electrically shorted circuits at high temperatures and voltages

Engineering Contradiction:
Improvemoisture resistanceVSAvoidfilm structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs a composite film structure consisting of alternating organic and inorganic layers. The organic layers (e.g., APHO, Parylene-C, CYTOP) provide moisture barrier properties, while the inorganic layers (e.g., Al2O3, SiO2, SiN) provide mechanical strength and adhesion. This composite architecture achieves superior moisture resistance (WVTR < 10^-4 g/m²/day) compared to conventional single-material films, resolving the contradiction between reliability and material simplicity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent uses thin film coatings (total thickness 50-500 nm) deposited on semiconductor contacts to create a protective barrier against moisture ingress. These thin films conformally coat the contact surfaces and surrounding areas, providing effective moisture protection without significantly increasing device complexity or size. The flexible film structure adapts to the underlying contact geometry while maintaining protective functionality.

Inventive Principle:
Principle #30Flexible shells and thin films

2Reliability

If thicker films are used to improve moisture protection, then moisture repelling properties improve, but dielectric constant increases causing higher losses at high frequencies

Engineering Contradiction:
Improvemoisture barrier performanceVSAvoiddielectric loss
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The composite film structure allows achieving high moisture barrier performance with low dielectric loss by combining materials with complementary properties. The organic layers provide excellent moisture barrier properties with low dielectric constants (εr < 2.1), while the inorganic layers provide mechanical support. This composite approach enables thin film thickness (50-500 nm) to achieve WVTR < 10^-4 g/m²/day without significant dielectric loss, resolving the contradiction between moisture protection and energy loss.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the dielectric constant parameter by selecting organic materials with εr < 2.1 (e.g., APHO, Parylene-C, CYTOP) and controlling film thickness to 50-500 nm. This parameter optimization ensures that the moisture barrier function is achieved while maintaining low dielectric loss for high-frequency operation, directly addressing the contradiction between moisture protection and energy efficiency.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional dielectric films are used, then manufacturing process is simpler, but moisture diffusion into contacts occurs at temperatures above 50°C

Engineering Contradiction:
Improvemoisture diffusion resistanceVSAvoidfilm deposition complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent uses a composite film structure with organic and inorganic layers deposited in alternating sequence. The organic layers (APHO, Parylene-C, CYTOP) provide superior moisture barrier properties with WVTR < 10^-4 g/m²/day, while the inorganic layers (Al2O3, SiO2, SiN) provide mechanical strength and adhesion. This composite approach achieves effective moisture diffusion resistance at temperatures above 50°C while using established deposition techniques, balancing reliability and manufacturability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The inorganic layers serve as intermediary layers between the organic moisture barrier layers and the semiconductor substrate. These intermediary inorganic layers (Al2O3, SiO2, SiN) provide mechanical support, adhesion, and stress management, enabling the thin organic layers to function effectively as moisture barriers without compromising structural integrity. This intermediary approach facilitates the manufacturing of complex composite films using sequential deposition processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The APHO film effectively prevents moisture-induced shorts and transient currents, enabling the application of high voltages and supporting high-frequency operations by repelling moisture and maintaining low dielectric constant and high transition temperature, thus enhancing IC performance and reliability.

Implementation Method 1

an Aminated-Polyhydroxy organic (APHO) film that covers the contact... the APHO film exhibits moisture repelling properties of less than 10−4 grams per square meter per day

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Implementation Method 2

Moisture often diffuses at higher temperatures (e.g., >50° C.) into the areas of contacts on the semiconductor substrates... the APHO film effectively prevents moisture-induced shorts

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Data Source

PatentUS20240413098A1Multilayer moisture repelling films for front end FET applications
Publication Date: 2024.12.12 QORVO US INC
  • US20240413098A1 patent drawing
  • US20240413098A1 patent drawing
  • US20240413098A1 patent drawing

AI summary

Embodiments of an integrated circuit (IC) structure are disclosed. The IC structure includes a semiconductor substrate having an active region, a contact positioned over the active region, and an Aminated-Polyhydroxy organic (APHO) film that covers the contact. The APHO film prevents moisture from causing shorts and transient currents, thereby allowing high voltages to be applied to the contact.