Apparatus and method for hydrate-based wastewater treatment and cold storage

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Solution Overview

Problem

Existing wastewater treatment systems face challenges with complex processes, selectivity to pollutant types, high energy consumption, and inefficient hydrate nucleation, while conventional cold storage systems have low energy storage conversion rates and density.

Innovation Solution

A hydrate-based wastewater treatment and cold storage system incorporating a water chilling unit, heat exchange system, finned tube heat exchanger, and monitoring devices to facilitate solid-liquid phase change of hydrates for energy-efficient wastewater treatment and cold storage, utilizing a hydrate former like R141b for energy integration and pollutant separation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional wastewater treatment technologies are used, then treatment processes can handle various pollutants, but the treatment effect is poor and energy consumption increases

Engineering Contradiction:
Improvetreatment effectVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent utilizes the phase transition of hydrate from liquid to solid state during formation, which releases latent heat. This phase change process enables simultaneous wastewater treatment and cold energy storage, improving treatment effectiveness while reducing energy consumption by capturing and storing the thermal energy released during hydrate formation.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent converts the waste heat energy normally lost during wastewater treatment into useful cold energy storage. By using the latent heat released during hydrate formation to drive the treatment process and store cold energy, the system transforms what would be wasted thermal energy into a beneficial resource for both treatment and future cooling applications.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Quantity of substance

If conventional cold storage systems are used, then cold storage function is provided, but cold storage density is low and energy storage conversion rate is low

Engineering Contradiction:
Improvecold storage densityVSAvoidenergy storage conversion rate
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The patent employs phase transition of hydrate formation and decomposition to achieve high-density cold energy storage. The latent heat released during hydrate formation is captured and stored, enabling high energy density. When needed, the hydrate decomposes to release stored cold energy, achieving high conversion rates without the losses associated with conventional compression-based cold storage systems.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent changes the physical state parameters of the hydrate former substance, transitioning it between liquid and solid phases through controlled temperature and pressure changes. This parameter manipulation enables reversible energy storage and release, significantly improving both cold storage density and energy conversion efficiency compared to conventional isothermal storage methods.

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If hydrate-based wastewater treatment is used, then energy consumption is reduced and pollutant separation is achieved, but hydrate nucleation is slow

Engineering Contradiction:
Improveenergy consumptionVSAvoidhydrate nucleation speed
Core Design Contradiction:
Use of energy by moving objectVSSpeed

Solution Approach 1:

The patent introduces pre-formed hydrate seeds or nucleation agents into the wastewater treatment system before the main hydrate formation process. This preliminary action provides ready-made nucleation sites that accelerate the hydrate formation kinetics, overcoming the slow natural nucleation rate while maintaining the energy-efficient operation of the hydrate-based treatment system.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses a hydrate former substance as an intermediary that facilitates the phase change process. This intermediary substance promotes rapid nucleation and crystal growth by providing a template structure for hydrate formation, thereby accelerating the overall process while maintaining low energy consumption characteristics of the hydrate-based system.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Adaptability or versatility

If conventional wastewater treatment is used, then treatment process can be implemented, but selectivity to types of pollutants limits applicability

Engineering Contradiction:
Improveapplicability to diverse wastewaterVSAvoidprocess complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent employs a universal hydrate-based treatment mechanism that functions across diverse wastewater types without requiring system reconfiguration. The hydrate formation process inherently separates contaminants from water based on physical chemistry principles that apply to organic, inorganic, and mixed pollutant types, providing broad applicability while maintaining relatively simple system architecture compared to multiple specialized treatment trains.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves efficient wastewater treatment and cold storage with reduced energy consumption, high pollutant removal efficiency, and multiple energy utilization, suitable for diverse wastewater types without secondary pollution, by leveraging the latent heat of hydrate phase change and continuous airflow disturbance for hydrate nucleation.

Implementation Method 1

a hydrate can be correspondingly formed at a relatively high temperature and atmospheric pressure by using a respective hydrate former, so as to separate purified water from impurities in the wastewater

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

By using a hydrate-based wastewater treatment system, a hydrate can be correspondingly formed

Methodology Applied
Scientific EffectHydrate formation: Hydrates

Implementation Method 3

the energy consumed by the wastewater treatment can be fully utilized, thereby achieving energy saving, emission reduction, and multiple utilization of the energy

Methodology Applied
Scientific EffectLatent heat: Latent Heat

Implementation Method 4

Bubbles are generated by the gas generator at the bottom of the inner tank of the wastewater treatment and cold storage tank for continuous airflow disturbance on the mixture of the hydrate former and the wastewater in the wastewater treatment and cold storage tank, so as to induce the hydrate nucleation

Methodology Applied
Scientific EffectNucleation: Nucleation

Implementation Method 5

the secondary refrigerant being conveyed by the first solution pump to the wastewater treatment and cold storage tank through the first flow meter, the first one-way valve, and the second two-way valve, and exchanging heat with a mixture of the hydrate former and the wastewater through the evaporator coil

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Data Source

PatentUS11939238B2Apparatus and method for hydrate-based wastewater treatment and cold storage
Publication Date: 2024.03.26 DALIAN UNIV OF TECH
  • US11939238B2 patent drawing
  • US11939238B2 patent drawing
  • US11939238B2 patent drawing

AI summary

The present disclosure provides an apparatus and a method for hydrate-based wastewater treatment and cold storage. The apparatus for hydrate-based wastewater treatment and cold storage includes a water chilling unit, a hydrate-based cold storage tank, an airflow disturbance device, a water layer positioning system, a spraying system, a suction filtration system, a heat exchange system, and a system monitoring device. The water chilling unit provides a secondary refrigerant at a low temperature. The secondary refrigerant flows through an evaporator coil in the hydrate-based cold storage tank for heat exchange. The airflow disturbance device induces hydrate nucleation. The water layer positioning system positions a contact surface between a water layer and a hydrate former after hydrate decomposition to facilitate drawing and separation of the treated upper water layer. The spraying system and the suction filtration system enhance the solid-liquid separation efficiency to improve the removal rate of pollutants.