Aprotic Solvent Stabilization of Hydrolytically Unstable Benefit Agents

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Solution Overview

Problem

Benefit agents in compositions are susceptible to hydrolysis during storage, leading to breakdown and instability, which affects consumer experience by providing unpredictable performance.

Innovation Solution

Incorporating an aprotic solvent with a molecular weight between 70 and 250, specifically propylene glycol carbonate, to stabilize benefit agents with nucleophilically or hydrolytically unstable bonds, often used in conjunction with detergent adjunct ingredients in detergent compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If benefit agents are used in compositions, then consumer desired benefits are provided, but the benefit agents are susceptible to hydrolysis by other components present in the product

Engineering Contradiction:
Improvebenefit agent stabilityVSAvoidhydrolysis breakdown
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces an aprotic solvent as an intermediary substance that mediates between the benefit agent and other composition components. The aprotic solvent creates a protective environment that prevents harmful hydrolysis reactions while allowing the benefit agent to maintain its function. This resolves the contradiction by adding a mediating substance that blocks the harmful interaction without eliminating the benefit agent's effectiveness.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Stability of the object's composition

If benefit agents are stable during storage, then consistent performance is provided, but benefit agents often break down upon storage

Engineering Contradiction:
Improvebenefit agent stabilityVSAvoidperformance consistency
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent changes the chemical environment parameters by introducing an aprotic solvent with specific properties (low water content, specific polarity). This parameter change in the composition's chemical environment stabilizes the benefit agent's molecular structure during storage, preventing hydrolysis and ensuring consistent performance characteristics throughout the product's shelf life.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If aprotic solvent is added to stabilize benefit agents, then hydrolysis is prevented, but composition formulation complexity increases

Engineering Contradiction:
Improvebenefit agent stabilityVSAvoidcomposition formulation
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent selects aprotic solvents that serve multiple functions: they stabilize benefit agents by preventing hydrolysis, maintain product viscosity, and are compatible with other composition components. This multi-functionality reduces the need for additional separate stabilizing agents, thereby limiting the increase in formulation complexity while achieving the desired stability improvement.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of aprotic solvents significantly improves the stability of benefit agents, ensuring consistent performance across the product's lifetime by preventing hydrolysis, thus enhancing consumer satisfaction.

Implementation Method 1

the stability of benefit agents having at least one hydrolytically unstable bond in compositions can be improved by the presence of specific solvents, namely aprotic solvents

Methodology Applied
Scientific EffectHydrolysis prevention through aprotic solvent environment: Solvation

Data Source

PatentUS9556406B2Compositions comprising benefit agent and aprotic solvent
Publication Date: 2017.01.31 MILLIKEN & CO
  • US9556406B2 patent drawing
  • US9556406B2 patent drawing
  • US9556406B2 patent drawing

AI summary

Composition comprising a benefit agent and an aprotic solvent, wherein the benefit agent comprises at least one nucleophilically and/or hydrolytically unstable bond.