Aqueous Acidic Hard-Surface Composition with Formic Acid for Shine

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Solution Overview

Problem

Existing hard surface cleaning compositions face challenges in achieving both good anti-bacterial performance and shine performance due to the negative effects of high citric acid and amine oxide surfactant levels on shine, and there is a need for an environmentally friendly alternative to quaternary ammonium compounds.

Innovation Solution

An aqueous acidic hard surface cleaning liquid composition comprising amine oxide surfactant, citric acid, and formic acid, with a pH range of 1.9 to 2.5, allowing for lower levels of citric acid and amine oxide while maintaining effective shine and anti-bacterial performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high levels of citric acid are used, then anti-bacterial performance is improved, but shine performance deteriorates and surfaces feel sticky

Engineering Contradiction:
Improveanti-bacterial performanceVSAvoidshine performance
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the chemical composition parameters by introducing formic acid as an additional acid component and optimizing the citric acid concentration to a specific range (0.1-1.0%) rather than using high levels. This parameter optimization resolves the contradiction by maintaining anti-bacterial efficacy through the combined acid system while preventing the sticky residue and shine degradation caused by excessive citric acid.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite acid system combining citric acid and formic acid in specific proportions. This composite approach allows the formulation to achieve effective anti-bacterial performance through the synergistic action of both acids while using lower overall acid concentrations, thereby preserving surface shine and avoiding the sticky feel associated with high citric acid alone.

Inventive Principle:
Principle #40Composite materials

2Productivity

If high levels of amine oxide surfactant are used, then cleaning performance is improved, but shine performance deteriorates

Engineering Contradiction:
Improvecleaning performanceVSAvoidshine performance
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent optimizes the amine oxide surfactant concentration to a specific range (0.01-1.0%) rather than using high levels. This parameter optimization maintains adequate cleaning performance while preventing the shine degradation that occurs with excessive surfactant concentrations, resolving the contradiction between cleaning efficacy and surface appearance.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If quaternary ammonium compounds are used, then anti-bacterial performance is improved, but environmental friendliness deteriorates

Engineering Contradiction:
Improveanti-bacterial performanceVSAvoidenvironmental friendliness
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and eliminates quaternary ammonium compounds from the formulation entirely, replacing their anti-bacterial function with a combination of optimized citric acid and formic acid. This removal of the harmful substance resolves the contradiction by maintaining effective anti-bacterial performance through environmentally friendly acid-based mechanisms.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves good shine and anti-bacterial performance without using quaternary ammonium compounds, providing a more environmentally friendly solution.

Implementation Method 1

amphoteric surfactant or a mixture of anionic and nonionic surfactants... amine oxide surfactant

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Implementation Method 2

citric acid, and formic acid wherein the composition has a pH in the range of from 1.9 to 2.5

Methodology Applied
Scientific EffectAcid dissociation: Electrolyte

Data Source

PatentUS20250257288A1Aqueous acidic hard surface cleaning liquid composition
Publication Date: 2025.08.14 PROCTER & GAMBLE CO
  • US20250257288A1 patent drawing
  • US20250257288A1 patent drawing

AI summary

An aqueous acidic hard surface cleaning liquid composition containing amine oxide surfactant, citric acid and formic acid.