Aqueous Basecoat Jet Disintegration for Overspray Reduction

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Solution Overview

Problem

Conventional coating methods in the automotive industry face inefficiencies, including overspray, streaky appearances, bubbling, and pinhole formation, particularly when using aqueous basecoat compositions, which affect the quality and appearance of coated surfaces.

Innovation Solution

An aqueous, one-pack coating composition is developed, comprising self- or externally crosslinkable polymers, polymeric surface-active agents, and organic rheology control agents, with specific viscosity and solids content ranges, and excluding platelet-shaped particulate materials, to create a jet that disintegrates into droplets at a controlled distance, ensuring optimal coating and minimizing defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional atomizing methods (rotary atomizer, air atomizer, airless device) are used, then coating application is achieved, but overspray increases and application efficiency decreases

Engineering Contradiction:
Improveapplication efficiencyVSAvoidoverspray
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The coating composition jet is segmented into droplets through controlled disintegration at a specific distance from the application device, creating a distribution of droplet sizes that optimizes deposition efficiency and reduces overspray

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the physical parameters of the coating composition (viscosity between 500-2000 mPa·s, solids content between 10-20 wt.%) to control jet disintegration behavior and droplet formation, improving application efficiency and reducing overspray

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If jet disintegration into droplets is forced by coupling vibrations, then droplet distribution is improved, but disintegration distance becomes insufficient

Engineering Contradiction:
Improvedroplet distributionVSAvoiddisintegration distance
Core Design Contradiction:
Manufacturing precisionVSLength of stationary object

Solution Approach 1:

Vibrations are coupled to the coating composition jet to control disintegration into droplets, achieving uniform droplet distribution while maintaining adequate disintegration distance for proper coating application

Inventive Principle:
Principle #18Mechanical vibration

Solution Approach 2:

The system dynamically balances jet velocity, vibration frequency, and disintegration distance to achieve optimal droplet formation, allowing the jet to disintegrate at the correct distance while maintaining precision droplet distribution

Inventive Principle:
Principle #15Dynamics

3Manufacturing precision

If continuous region of coating composition jet is used for coating, then coating result is improved, but application distance must be very small

Engineering Contradiction:
Improvecoating qualityVSAvoidapplication distance
Core Design Contradiction:
Manufacturing precisionVSLength of moving object

Solution Approach 1:

The viscosity and solids content parameters of the coating composition are optimized to enable the jet to maintain its continuous structure over a longer distance while still achieving proper coating quality upon impact

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If aqueous basecoat compositions are used, then environmental compatibility is improved, but storage stability decreases due to premature curing

Engineering Contradiction:
Improveenvironmental compatibilityVSAvoidstorage stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

A curing agent is introduced as an intermediary component that remains dormant during storage and only activates under specific conditions (temperature, humidity, or catalyst presence), preventing premature curing while maintaining environmental compatibility of the aqueous formulation

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The pH value and ionic strength of the aqueous basecoat composition are controlled to stabilize the polymer and prevent premature crosslinking, while still allowing curing to proceed when applied to the substrate

Inventive Principle:
Principle #35Parameter changes

5Manufacturing precision

If platelet-shaped particulate materials are included, then coating composition is enhanced, but streaky appearance and surface defects occur

Engineering Contradiction:
Improvecoating uniformityVSAvoidsurface defects
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

Platelet-shaped particulate materials are removed from the coating composition to eliminate the source of streaky appearance and surface defects such as bubbling and pinhole formation

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The coating composition is formulated with uniformly shaped particles (non-platelet morphology) that distribute more evenly in the aqueous medium, preventing the formation of surface defects and achieving a uniform coating appearance

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves a sharp-edged pattern with minimal overspray and surface defects, providing a high-quality, uniform coating that is storage-stable and suitable for automotive applications without premature curing, ensuring improved appearance and efficiency.

Implementation Method 1

the coating composition jet initially has a continuous region in the jet direction until the jet reaches a disintegration distance, whereupon after the disintegration distance after emission from the application device, the coating medium jet then disintegrates naturally (by natural disintegration according to Rayleigh as is known) into droplets

Methodology Applied
Scientific EffectRayleigh instability: Plateau-Rayleigh Instability

Implementation Method 2

at least one polymeric surface-active agent

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 3

at least one organic rheology control agent selected from the group consisting of (meth)acrylic acid-(meth)acrylate copolymer rheology control agents and polyurethane rheology control agents

Methodology Applied
Scientific EffectRheology control: Non-Newtonian Fluids

Data Source

PatentEP4217426B1Aqueous, low solids basecoat compositions
Publication Date: 2024.08.21 BASF COATINGS GMBH

AI summary

The invention relates to an aqueous, one-pack coating composition comprising at least one polymer selected from the group consisting self-crosslinkable polymers and externally crosslinkable polymers; at least one crosslinking agent for crosslinking the at least one polymer, if the at least one polymer is an externally crosslinkable polymer; at least one polymeric surface-active agent, and at least one organic rheology control agent selected from the group consisting of (meth)acrylic acid-(meth)acrylate copolymer rheology control agents and polyurethane rheology control agents, wherein the total solids content of the coating composition is from 7.5 wt.-% to 11.5 wt.-%; the viscosity at 23 °C is from 2000 mPas to 12000 mPas at a shear rate of 0.1 s-1; the amount of the at least one polymeric surface-active agent is from 0.5 to 25 wt.-% based on the total solids content of the coating composition; the amount of the at least one organic rheology control agent is from 5 to 12 wt.-% based on the total solids content of the coating composition; and the coating composition does not contain platelet- shaped particulate material having a median particle size D50 (determined by laser diffraction) of 2 µm or more. The invention further relates to a method of producing a coating, preferably a multi-layer coating, making use of an application method wherein the coating composition is applied by a device producing a coating composition jet. Moreover, the invention relates to thus coated substrates.