Aqueous Binder Composition for Fibrous Materials with Recyclable Process Water

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Solution Overview

Problem

Traditional phenol formaldehyde resin (PFR) binders used in manufacturing fibrous materials like glass wool and rock wool release toxic substances such as formaldehyde and phenol, causing environmental concerns and health risks, and do not effectively prevent putrefaction of process water, leading to inefficiencies in recycling and increased costs.

Innovation Solution

An aqueous heat-curable binder composition comprising reducing sugars, amino acids, and aldehyde compounds with a minimum inhibitory concentration (MIC) of 1% or less, which undergoes the Maillard reaction to form Melanoidins, providing enhanced mechanical properties and preservative ability, allowing for the recycling of process water without putrefaction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If phenol formaldehyde resin (PFR) is used as a binder, then physical properties such as adhesion strength are improved, but toxic materials such as formaldehyde and phenol are released causing environmental and health problems

Engineering Contradiction:
Improveadhesion strengthVSAvoidtoxic material release
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful effect of aldehyde release into a beneficial preservative function. The aldehyde compound with MIC ≤1% not only provides binding function but also prevents putrefaction of process water, turning a previously harmful byproduct into a useful preservative agent that enables water recycling.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent changes the chemical composition parameters by using specific aldehyde compounds with minimum inhibitory concentration (MIC) of 1% or less, replacing traditional PFR with a new chemical system that maintains binding strength while eliminating toxic phenol and reducing formaldehyde release through controlled aldehyde selection.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If traditional PFR binder is used, then preservative effect is provided preventing putrefaction, but process water cannot be recycled due to toxic contamination and odor

Engineering Contradiction:
Improvepreservative effectVSAvoidodor and toxic contamination
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and eliminates the harmful components (phenol and excessive formaldehyde) from the binder system while retaining the essential preservative function through carefully selected aldehyde compounds with MIC ≤1%, separating the beneficial preservative effect from the harmful toxic effects.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The aldehyde compound serves dual functions: as a binder component and as a preservative agent. The preservative effect that previously only prevented putrefaction now also enables water recycling by controlling microbial growth without the harmful side effects of traditional PFR.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Object-generated harmful factors

If eco-friendly binder components are used, then toxic material release is reduced, but preservative effect is almost nonexistent requiring separate treatment facilities

Engineering Contradiction:
Improvetoxic material releaseVSAvoidpreservative effect
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The aldehyde compound performs multiple functions simultaneously: it acts as a binder component providing adhesion, and as a preservative agent preventing putrefaction of process water. This multi-functionality eliminates the need for separate treatment facilities while maintaining eco-friendliness.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent creates a composite binder system combining reducing sugars, amino acids, and aldehyde compounds with MIC ≤1%, where the aldehyde component provides both binding and preservative functions that the other components alone cannot achieve, creating a synergistic effect.

Inventive Principle:
Principle #40Composite materials

4Ease of manufacture

If PFR is used for binding fibrous materials, then manufacturing cost is reduced, but separate facilities are needed to treat process water preventing recycling

Engineering Contradiction:
Improvemanufacturing costVSAvoidfacility complexity for water treatment
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The binder composition provides self-service by incorporating preservative functionality directly into the binding agent. The aldehyde compound with MIC ≤1% automatically prevents putrefaction of process water, eliminating the need for external treatment facilities and enabling straightforward water recycling.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The binder composition achieves equal or better physical properties than PFR with reduced toxicity and odor, enabling the recycling of process water, significantly enhancing water resistance, tensile strength, hardness, and dust rate of the final product while minimizing environmental impact.

Implementation Method 1

the binder solution has preservative ability... process water can be recycled without putrefaction

Methodology Applied
Scientific EffectPreservative: Preservative

Implementation Method 2

An aqueous heat-curable binder composition comprising reducing sugars, amino acids, and aldehyde compounds... which undergoes the Maillard reaction to form Melanoidins

Methodology Applied
Scientific EffectMaillard reaction: Chemical Bonding

Data Source

PatentEP3156467B1Aqueous binder composition having recyclable process water, and method for binding fibrous material by using same
Publication Date: 2022.09.21 KCC CORP
  • EP3156467B1 patent drawingFigure 1

AI summary

The present invention relates to aqueous binder composition capable of recycling process water and method for binding fibrous materials by using the same, and relates to an aqueous binder composition comprising one or more reducing sugars, one or more amino acids and aldehyde compounds with minimum inhibitory concentration (MIC) 1% or less and a method for binding fibrous materials by using the same. The binder composition of the present invention provides equal or better physical properties with lower price compared to traditional phenol formaldehyde resin (PFR), does not include or release toxic materials such as formaldehyde or phenol, may decrease bad odor which is a vulnerable point of traditional PFR during manufacturing and remarkably enhances the mechanical properties such as water resistance, tensile strength and hardness of the manufactured product, and is economical since process water can be recycled without putrefaction which occurs during the manufacturing process of binding of fibrous materials using the binder component since the binder solution has preservative ability.