Aqueous Cleaning Composition with Phosphate and Ester

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Solution Overview

Problem

Existing solvent-based and caustic acid/alkali-based cleaning compositions are hazardous, requiring special handling and storage, and existing non-toxic aqueous compositions for removing organic coatings lack improved cleaning and coating-removal effectiveness.

Innovation Solution

An aqueous composition comprising a compound of formula (I), an ester, a surfactant, water, and optionally a rheology control agent and anti-foaming agent, with water content greater than 80% but less than 99% by weight, forming a stable and optically transparent emulsion for effective surface cleaning and coating removal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If solvent-based compositions (methylene chloride or other volatile organic compounds) are used for cleaning surfaces and removing coatings, then effective cleaning and coating removal is achieved, but the compositions become toxic, irritant, and require special storage and handling procedures

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidtoxicity and irritancy
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces harmful solvent-based compositions with water-based compositions, converting the harmful organic solvents into benign water as the primary solvent. This substitution maintains cleaning effectiveness while eliminating toxicity and irritancy, allowing safe handling without special protective equipment

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent changes the fundamental parameter of the solvent from organic volatile compounds to water, fundamentally altering the safety profile while maintaining functional performance. This parameter change enables the composition to be non-toxic and non-irritant while still effectively removing coatings and cleaning surfaces

Inventive Principle:
Principle #35Parameter changes

2Reliability

If caustic acids or alkalis are used in aqueous cleaning compositions, then cleaning and coating removal effects are achieved, but substantial health and safety concerns arise requiring special storage and handling procedures

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidhealth and safety risks
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent eliminates caustic acids and alkalis from the composition, replacing them with non-caustic aqueous components. This conversion removes the health and safety hazards associated with caustic substances while preserving the cleaning and coating removal effectiveness through alternative non-caustic mechanisms

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent uses mild, non-caustic ingredients that are safer and more environmentally friendly, replacing the need for harsh chemicals. These gentler components achieve the desired cleaning effect without creating long-term health and safety concerns or requiring special handling procedures

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Object-affected harmful factors

If water content in aqueous cleaning compositions is increased beyond 80% by weight, then safety and environmental friendliness improve, but the composition may become unstable or lose optical clarity

Engineering Contradiction:
Improvetoxicity reductionVSAvoidemulsion stability and optical clarity
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent introduces surfactants as intermediary substances that enable high water content formulations to remain stable and optically clear. These surfactants act as mediators between water and other composition components, preventing phase separation and maintaining transparency even when water constitutes the majority of the formulation

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the water content parameter to exceed 80% by weight while simultaneously adjusting other parameters (surfactant concentration, pH, temperature) to maintain composition stability and optical clarity. This multi-parameter optimization allows achieving both high safety through water dominance and functional stability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides effective cleaning and coating removal without toxicity or irritancy, maintaining optical clarity and stability, and can be thickened without impairing cleaning properties, offering a safer and more environmentally friendly alternative with improved performance.

Implementation Method 1

for plasticising or softening coatings or other surface-adhered materials prior to stripping or mechanical removal thereof from the surface

Methodology Applied
Scientific EffectPlasticisation: Plasticity

Implementation Method 2

The said composition exists as a stable, preferably optically transparent, emulsion which does not separate into oil and water phases

Methodology Applied
Scientific EffectEmulsion: Emulsion

Implementation Method 3

an aqueous composition comprising: (a) the following components (i) and (ii): (i) at least one compound of formula (I)... (ii) an ester... (b) a surfactant

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 4

The use of a rheology control agent to thicken the composition to the form of a gel can increase its viscosity without impairing its cleaning properties

Methodology Applied
Scientific EffectRheology control: Rheopecty

Data Source

PatentEP3158013B1Aqueous composition for cleaning or removing coatings
Publication Date: 2019.03.27 ECO SOLUTIONS LTD
  • EP3158013B1 patent drawingFigure 1
  • EP3158013B1 patent drawingFigure 2
  • EP3158013B1 patent drawingFigure 3

AI summary

An aqueous composition for cleaning surfaces, for removing coatings from surfaces, or for plasticising or softening coatings or other surface-adhered materials prior to stripping or mechanical removal thereof from the surface, comprises a trialkyi or triaryl phosphate, a dibasic or tribasic carboxylic acid ester, and greater than 80% by weight of water. The composition is useful in removing grease, waxes, oil, resins, tar, ink, magic marker ink, paint (including spray-paint), varnish, lacquer, stains (including wood staining compositions applied to a wooden surface), dirt, mould or foodstuffs from surfaces.