Aqueous CO2 Solution Sequestration in Subsurface Formations

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Solution Overview

Problem

Current methods for subsurface CO2 sequestration face challenges due to the buoyancy of pure CO2, which limits its sequestration to specific geological traps and reduces the efficiency of CO2 floods.

Innovation Solution

The method involves injecting an aqueous CO2 solution with a density greater than formation water and hydrocarbons, allowing it to sink and sequester CO2 in subsurface formations, thereby avoiding channeling towards production wells and increasing the amount of CO2 stored.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If pure CO2 is injected into subsurface formations, then CO2 sequestration can be achieved, but the CO2 rises due to buoyancy and channels towards production wells, reducing sequestration efficiency

Engineering Contradiction:
Improveamount of CO2 sequesteredVSAvoidsequestration efficiency
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent changes the physical-chemical parameters of CO2 by dissolving it in an aqueous solvent to form a dense aqueous CO2 solution. This solution has a density greater than formation water, fundamentally altering the buoyancy characteristics of injected CO2 from positive to negative buoyancy, thereby preventing upward migration and channeling toward production wells.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces an aqueous solvent as an intermediary medium to transport CO2 into subsurface formations. Instead of injecting pure CO2 gas or supercritical fluid directly, the CO2 is dissolved in water to create a dense aqueous solution that serves as a carrier, enabling controlled subsurface injection and distribution while preventing unwanted migration.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If pure CO2 is injected into subsurface formations, then CO2 storage is achieved, but it is restricted to locations with specific trap types and impervious cap rock

Engineering Contradiction:
Improveamount of CO2 storedVSAvoidsequestration location flexibility
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

By changing the density parameter of CO2 through dissolution in aqueous solvent, the patent enables injection into a broader range of subsurface formations that do not require traditional positive buoyancy traps or impervious cap rock. The negative buoyancy of the aqueous CO2 solution allows it to sink and pool in various geological settings, significantly expanding suitable sequestration locations.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If traditional CO2 floods are conducted, then hydrocarbon production is maintained, but CO2 channels preferentially towards the producing well, reducing both CO2 flood efficiency and ultimate hydrocarbon recovery

Engineering Contradiction:
Improvehydrocarbon productionVSAvoidCO2 flood efficiency
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The patent changes the density parameter of the injected fluid by using aqueous CO2 solution instead of pure CO2. This creates negative buoyancy relative to formation water, causing the injected fluid to sink rather than rise and channel toward the producing well. This improves sweep efficiency and hydrocarbon recovery while maintaining production.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances CO2 sequestration efficiency by ensuring the CO2 solution remains negatively buoyant, preventing channeling, and increasing hydrocarbon production through pressure support, ultimately leading to greater CO2 storage capacity in subsurface formations.

Implementation Method 1

The aqueous CO2 solution has a density at least greater than formation water in the subsurface formation... the aqueous CO2 solution is negatively buoyant in the subsurface formation. This causes the aqueous CO2 solution to sink in the subsurface formation, rather than rise.

Methodology Applied
Scientific EffectBuoyancy: Archimedes' Principle (Buoyancy)

Data Source

PatentUS12264559B2Subsurface sequestration of CO2 in subsurface formations
Publication Date: 2025.04.01 SAUDI ARABIAN OIL CO
  • US12264559B2 patent drawing
  • US12264559B2 patent drawing
  • US12264559B2 patent drawing

AI summary

A method of subsurface sequestration of CO2 in a subsurface formation, the method including: producing formation water and hydrocarbons from a first well located within the first region while concurrently injecting an aqueous CO2 solution into a second well located within the second region, wherein the subsurface formation comprises a first region and a second region, the first region and the second region being fluidly connected, and the second region is at a greater depth than the first region and comprises at least one of the subsurface sequestration locations; and allowing the aqueous CO2 solution to sink as a negatively buoyant fluid below the formation water and the hydrocarbons, thereby sequestering the CO2 in the second region of the subsurface formation and wherein the aqueous CO2 solution has a greater density than the formation water and the hydrocarbons, making the aqueous CO2 solution negatively buoyant in the subsurface formation.