Aqueous Two-Component Coating Erosion Resistance

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Solution Overview

Problem

Current coating compositions for erosion resistance face challenges in achieving high erosion resistance while maintaining a good environmental profile and freedom of formulation, particularly in applications like wind turbine rotor blades and aircraft, where they are sensitive to additives and require low organic solvent content.

Innovation Solution

An aqueous two-component coating composition comprising an aqueous dispersion of polymeric resin and polycarbonate diol combined with a polyisocyanate-modified polyester, which provides excellent erosion resistance and a good environmental profile without the need for excessive film thickness or high temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If film thickness is increased to improve erosion resistance, then erosion resistance is improved, but weight increases

Engineering Contradiction:
Improveerosion resistanceVSAvoidcoating weight
Core Design Contradiction:
ReliabilityVSWeight of moving object

Solution Approach 1:

The patent changes the chemical composition parameters of the coating system by using aqueous polymeric resin dispersions with specific molecular weights and functionality ratios, along with polyisocyanate crosslinking agents. This chemical parameter optimization enables achieving high erosion resistance through improved molecular network structure rather than increased thickness, thus reducing coating weight while maintaining reliability.

Inventive Principle:
Principle #35Parameter changes

2Object-generated harmful factors

If organic solvent content is reduced to improve environmental profile, then environmental compatibility is improved, but formulation freedom and compatibility with pigments/fillers deteriorates

Engineering Contradiction:
Improveorganic solvent emissionsVSAvoidformulation freedom
Core Design Contradiction:
Object-generated harmful factorsVSAdaptability or versatility

Solution Approach 1:

The patent changes the solvent system parameter from organic-based to aqueous-based, using water as the primary dispersion medium. This parameter change is compensated by optimizing other formulation parameters including resin solids content (40-80%), pH control (7-9), and use of specific dispersants and surfactants, thereby maintaining formulation freedom and compatibility with pigments and fillers while achieving low VOC emissions (<250 g/l).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces aqueous dispersion technology as an intermediary system, where polymeric resins are dispersed in water with the aid of surfactants and dispersants. These intermediary substances enable the aqueous system to achieve properties previously only attainable with organic solvents, including proper viscosity control, pigment wetting, and film formation, thus bridging the gap between environmental requirements and formulation flexibility.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-generated harmful factors

If low solvent content is used to improve environmental profile, then VOC content is reduced, but sensitivity to additives and risk of separation increases

Engineering Contradiction:
ImproveVOC contentVSAvoidcomposition stability
Core Design Contradiction:
Object-generated harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent optimizes the aqueous dispersion parameters including pH (7-9), ionic strength, and surfactant concentration to ensure colloidal stability. By controlling these parameters, the system achieves low VOC content while preventing phase separation and maintaining composition stability during storage and application.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements quality control feedback mechanisms by monitoring key parameters such as pH, viscosity, and particle size distribution during formulation and storage. This continuous monitoring and adjustment of critical parameters ensures that the aqueous coating system maintains stability and prevents separation, allowing for reduced VOC content without compromising composition integrity.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating composition achieves outstanding erosion resistance and a high-grade environmental profile, allowing for low-temperature curing and reduced sensitivity to additives, thus addressing the limitations of existing compositions.

Implementation Method 1

An aqueous two-component coating composition comprising an aqueous dispersion of polymeric resin and polycarbonate diol combined with a polyisocyanate-modified polyester

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentUS10093825B2Aqueous two-component coating compositions and high erosion resistance coatings produced therefrom
Publication Date: 2018.10.09 AKZO NOBEL COATINGS INT BV

AI summary

The present invention relates to an aqueous two-component coating composition comprising (1) an aqueous paint base component comprising (A) at least one aqueous dispersion of at least one polymeric resin and (B) at least one polycarbonate diol and also (2) a hardener component comprising (C) at least one polyisocyanate-modified polyester having an isocyanate content of 4% to 15%. The present invention also relates to a method for coating on substrates by applying the coating composition and also to the use thereof.