Aqueous Gel Ballpoint Pen Ink Flow Pore and Storage Modulus Control

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional aqueous gel ballpoint pens with needle type ballpoint pen tips suffer from reduced storage stability and writing performance due to ink viscosity increase and pigment sedimentation over time, especially when the ink flow pore diameter is small.

Innovation Solution

The solution involves controlling the storage modulus of the aqueous gel ink within specific ranges (1.3≦G′≦16r−3.2 Pa) in conjunction with optimizing the ink flow pore diameter (0.24≦r≦0.64 mm) to ensure stable ink flow and prevent pigment sedimentation, thereby enhancing storage stability and writing performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If the ink flow pore diameter is reduced in a needle type ballpoint pen tip, then the pen can be manufactured with smaller dimensions and finer line output, but the storage stability deteriorates due to increased ink viscosity and pigment sedimentation

Engineering Contradiction:
Improveink flow pore diameterVSAvoidstorage stability
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling the storage modulus G' of the aqueous gel ink within the range 1.3 ≤ G' ≤ 16r−3.2 Pa, where r is the ink flow pore diameter. This parameter control prevents pigment sedimentation and maintains ink fluidity in small-diameter needle type tips while enabling fine line output and compact pen design

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If conventional aqueous gel inks are used in needle type ballpoint pen tips, then the pen can be produced with standard ink formulations, but the storage stability is insufficient due to ink viscosity increase over time

Engineering Contradiction:
Improveink formulation standardizationVSAvoidstorage stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent modifies the ink formulation parameters by controlling the storage modulus G' within a specific range that depends on the ink flow pore diameter. This ensures that even with standard needle type tip manufacturing, the ink maintains adequate fluidity and prevents clogging during storage

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary anti-action by pre-controlling the storage modulus of the ink before it is put into the pen. This preventive measure counteracts the natural tendency of ink to increase in viscosity and cause sedimentation during storage, ensuring stable performance without requiring special tip designs

Inventive Principle:
Principle #9Preliminary anti-action

3Reliability

If the storage modulus of ink is increased to prevent pigment sedimentation, then the storage stability improves, but the ink fluidity through small ink flow pores deteriorates

Engineering Contradiction:
Improvestorage stabilityVSAvoidink fluidity
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent resolves this contradiction by establishing an optimal range for storage modulus G' that balances both requirements. The formula 1.3 ≤ G' ≤ 16r−3.2 Pa ensures that the ink has sufficient viscosity to prevent pigment sedimentation while maintaining enough fluidity to flow through small ink flow pores in needle type tips

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly improves the storage stability and writing performance of aqueous gel ballpoint pens with needle type tips by maintaining ink fluidity and preventing pigment localization, ensuring consistent line density and reducing thin spots in written lines.

Implementation Method 1

an ink flow pore diameter r (unit: mm) in the ballpoint pen tip and a storage modulus G′ (unit: Pa) at 20° C. of the aqueous gel ink satisfy conditions represented by the following formulas (1) and (2): 0.24≦r≦0.64 (1), and 1.3≦G′≦16r−3.2 (2)

Methodology Applied
Scientific EffectStorage modulus: Viscoelasticity

Implementation Method 2

there has been proposed an aqueous ink for a ballpoint pen which contains xanthan gum and a noncrosslinked polyacrylic acid having a predetermined molecular weight and the like

Methodology Applied
Scientific EffectSteric hindrance:

Implementation Method 3

proposals for increasing the storage stability have been made

Methodology Applied
Scientific EffectElectrostatic repulsion:

Data Source

PatentUS7600937B2Aqueous gel ballpoint pen and method for the production thereof
Publication Date: 2009.10.13 ZEBRA
  • US7600937B2 patent drawing
  • US7600937B2 patent drawing
  • US7600937B2 patent drawing

AI summary

An aqueous gel ballpoint pen 1 having an ink-storage tube storing an aqueous gel ink containing a pigment as a coloring agent, and a ballpoint pen tip having a ball rotatably held at its leading end and also having an ink flow pore which is formed so that the aqueous gel ink flows from the ink-storage tube to the ball, wherein an ink flow pore diameter r (unit: mm) in the ballpoint pen tip and a storage modulus G′ (unit: Pa) at 20° C. of the aqueous gel ink satisfy conditions represented by the following formulas (1) and (2):0.24≦r≦0.64  (1), and1.3≦G′≦16r−3.2  (2).