Aqueous Ink Jet Composition Dispersion Stability

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Solution Overview

Problem

Ink jet compositions containing disperse dyes, such as C.I. Disperse Red 364, face issues with long-term storage stability and clogging of head filters and nozzles due to inferior dispersion stability, leading to the generation of foreign materials during storage and ejection.

Innovation Solution

An aqueous ink jet composition comprising C.I. Disperse Red 364, a material A (including compounds like ethylene oxide adducts of tristyrylphenol and polyalkylene glycols), and an anionic dispersant, specifically a sodium salt of naphthalenesulfonic acid formalin condensate, to improve dispersion and storage stability, preventing foreign material generation and nozzle clogging.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If C.I. Disperse Red 364 is used as a disperse dye in ink jet composition, then red-base coloring property is improved, but storage stability deteriorates and foreign materials are generated during long-term storage

Engineering Contradiction:
Improvecoloring propertyVSAvoidstorage stability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

A specific surfactant compound (formula 1 or 2) acts as an intermediary between C.I. Disperse Red 364 and the aqueous medium, preventing dye aggregation and foreign material generation at the gas-liquid interface during storage, thereby maintaining both coloring property and storage stability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical parameters by introducing specific surfactant compounds with defined molecular structures (formulas 1 and 2) and controlling their concentration ratios relative to the dye, which fundamentally alters the interfacial properties and prevents foreign material generation

Inventive Principle:
Principle #35Parameter changes

2Illumination intensity

If C.I. Disperse Red 364 is used in ink jet composition, then coloring property is improved, but ejection stability deteriorates due to nozzle clogging

Engineering Contradiction:
Improvecoloring propertyVSAvoidejection stability
Core Design Contradiction:
Illumination intensityVSEase of operation

Solution Approach 1:

The surfactant compound serves as a mediator that reduces surface tension and prevents dye precipitation at the nozzle and head filter, ensuring stable ejection while maintaining the excellent coloring property of C.I. Disperse Red 364

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

By controlling the concentration ratio of the surfactant to the dye within specific ranges (0.01≤XA/XD≤1.5 and 0.2≤XB/XD≤2.0), the patent optimizes ejection stability while preserving coloring performance

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If conventional dispersants are used with C.I. Disperse Red 364, then dispersion is improved, but foreign material generation at gas-liquid interface increases

Engineering Contradiction:
Improvedispersion stabilityVSAvoidforeign material generation
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a specifically designed surfactant compound as an intermediary that selectively prevents foreign material generation at the gas-liquid interface while maintaining dispersion stability, addressing the limitation of conventional dispersants

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite system combining C.I. Disperse Red 364 with specific surfactant compounds (formulas 1 or 2) and anionic dispersants, where the synergistic interaction prevents foreign material generation while maintaining dispersion stability

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition ensures stable ink ejection over time, enhances the quality of recorded matter, and prevents adverse effects on sublimation dyeing by maintaining the dispersion stability of C.I. Disperse Red 364, thereby improving storage and ejection stability.

Implementation Method 1

foreign materials are liable to be generated at a gas-liquid interface

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

foreign materials are liable to be generated at a gas-liquid interface, and as a result, clogging of a head filter and/or a nozzle in ink ejection

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Data Source

PatentUS11591489B2Aqueous ink jet composition
Publication Date: 2023.02.28 SEIKO EPSON CORP
  • US11591489B2 patent drawing
  • US11591489B2 patent drawing
  • US11591489B2 patent drawing

AI summary

An aqueous ink jet composition contains: C.I. Disperse Red 364; a material A which is at least one compound selected from the group consisting of a compound represented by the following formula (1), a compound represented by the following formula (2), an ethylene oxide adduct of tristyrylphenol, a derivative of the ethylene oxide adduct of tristyrylphenol, a polyalkylene glycol, and a derivative of the polyalkylene glycol; and an anionic dispersant.