Aqueous Ink Dynamic Surface Tension Control for High-Speed Recording

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Solution Overview

Problem

Existing aqueous inks for inkjet recording systems face challenges in achieving high image density and fixing ability, particularly on recording media with varying textures and permeation speeds, leading to issues like white stripes and insufficient image quality during high-speed recording.

Innovation Solution

An aqueous ink formulation comprising water, a water-soluble organic solvent, a water-insoluble coloring material, a surfactant, and a poor medium or salt, with specific dynamic surface tension characteristics to control the aggregation and permeation of the coloring material, ensuring high image density and fixing ability across different recording media.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If pigment particles are caused to aggregate on the surface of the recording medium to enhance image density, then image density is improved, but the area factor (surface coverage) becomes insufficient

Engineering Contradiction:
Improveimage densityVSAvoidarea factor
Core Design Contradiction:
Illumination intensityVSArea of stationary object

Solution Approach 1:

The patent changes the chemical composition parameters of the ink by introducing specific water-soluble organic solvents (acetone, methyl ethyl ketone, ethyl acetate) with controlled ratios. This composition adjustment modifies the ink's interaction with the recording medium, enabling simultaneous achievement of high image density and adequate surface coverage without excessive pigment aggregation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite ink formulation combining water, multiple water-soluble organic solvents, pigment particles, and surfactants. This composite material works synergistically to control pigment behavior, allowing the ink to achieve both high image density and sufficient area factor through the combined effects of its components.

Inventive Principle:
Principle #40Composite materials

2Area of stationary object

If the amount of ink applied is increased to achieve sufficient area factor, then surface coverage is improved, but drying time increases causing print-through

Engineering Contradiction:
Improvearea factorVSAvoiddrying time
Core Design Contradiction:
Area of stationary objectVSLoss of time

Solution Approach 1:

The patent modifies the ink's evaporation characteristics by incorporating water-soluble organic solvents with different volatility. The specific ratio of acetone, methyl ethyl ketone, and ethyl acetate creates an optimized evaporation profile that ensures rapid initial drying to prevent print-through, while maintaining sufficient surface coverage through controlled pigment deposition.

Inventive Principle:
Principle #35Parameter changes

3Area of stationary object

If the permeability of ink into the recording medium is improved to increase area factor, then surface coverage is enhanced, but image density becomes insufficient due to depth-wise permeation

Engineering Contradiction:
Improvearea factorVSAvoidimage density
Core Design Contradiction:
Area of stationary objectVSIllumination intensity

Solution Approach 1:

The patent adjusts the ink's rheological and chemical parameters by controlling the composition of water-soluble organic solvents and surfactant concentration. This creates an ink formulation with optimized permeation characteristics that allows controlled surface penetration to achieve adequate area factor while preventing excessive depth-wise permeation, thereby maintaining high image density.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If high-speed continuous recording is conducted, then productivity is improved, but white stripes occur due to insufficient drying time

Engineering Contradiction:
Improverecording speedVSAvoidimage quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent optimizes the ink's evaporation and drying parameters through the specific composition of water-soluble organic solvents. The controlled volatility profile enables rapid drying that keeps pace with high-speed recording, preventing the formation of white stripes and maintaining image quality even during continuous high-speed operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent ensures continuous effective drying action through the optimized solvent composition. The ink formulation maintains appropriate drying characteristics throughout the recording process, ensuring that each successive recording pass occurs on sufficiently dried previous passes, thereby preventing defects during high-speed continuous recording.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink achieves excellent image density and fixing ability on various recording media, preventing white stripes during high-speed recording by maintaining optimal dynamic surface tension and aggregation of the coloring material, even with small ink droplet volumes.

Implementation Method 1

a dynamic surface tension of the aqueous ink at a lifetime of 50 milliseconds determined by a maximum bubble pressure method is higher than 47 mN/m, and a dynamic surface tension at a lifetime of 5,000 milliseconds determined by the maximum bubble pressure method is 38 mN/m or lower

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 2

controlling the permeation of the ink into the recording medium and the aggregation of a coloring material in the ink

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentUS7699924B2Aqueous ink, ink jet recording method, ink cartridge, recording unit and ink jet recording apparatus
Publication Date: 2010.04.20 CANON KK
  • US7699924B2 patent drawing
  • US7699924B2 patent drawing
  • US7699924B2 patent drawing

AI summary

Provided herein is an aqueous ink, which is excellent in both image density and fixing ability irrespective of the kind of a recording medium even when the volume of an ink droplet is small and has such excellent properties that white stripes are not caused even when high-speed recording is conducted. The aqueous ink comprises at least water, a water-soluble organic solvent, a water-insoluble coloring material, a surfactant and a poor medium for the water-insoluble coloring material and/or a salt. The dynamic surface tension of the aqueous ink at a lifetime of 50 milliseconds determined by a maximum bubble pressure method is higher than 47 mN/m, and the dynamic surface tension at a lifetime of 5,000 milliseconds determined by the maximum bubble pressure method is 38 mN/m or lower.