Aqueous ink jet composition for textile printing

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Solution Overview

Problem

Aqueous inkjet inks containing disperse dyes face issues with low storage stability and jetting reliability due to dispersion stability problems, and the use of anionic dispersing agents like lignin sulfonic acid compromises water resistance and wet crock fastness of printed textiles.

Innovation Solution

Incorporating lignin into the aqueous inkjet ink composition, along with a disperse dye and a dispersant, to enhance dispersion stability and jetting reliability while maintaining acceptable water resistance and wet crock fastness, by controlling lignin concentration and using it as a synergist with dispersants to improve milling efficiency and particle size distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If anionic dispersing agents like lignin sulfonic acid are used to improve dispersion stability, then storage stability and jetting reliability are improved, but water resistance and wet crock fastness deteriorate

Engineering Contradiction:
Improvejetting reliabilityVSAvoidwater resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and removes the anionic dispersing agent (lignin sulfonic acid) from the ink composition that was causing the water resistance problem, while retaining the beneficial dispersing function through alternative means (optimized dispersant selection and lignin modification)

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical parameters of the dispersing system by modifying lignin (reducing sulfonic acid groups) and selecting specific dispersants with appropriate HLB values and molecular weights, thereby achieving dispersion stability without the harmful water resistance degradation

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If disperse dye is used for dyeing hydrophobic fibres, then colour fastness is improved, but storage stability and jetting reliability deteriorate due to dispersion instability

Engineering Contradiction:
Improvecolour fastnessVSAvoidstorage stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent creates a composite dispersing system combining modified lignin with specifically selected dispersants (non-ionic and/or anionic) that have complementary properties, achieving synergistic dispersion stability that prevents dye aggregation while maintaining jetting performance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes multiple parameters including dispersant HLB value (12-18), dispersant molecular weight (1000-10000), and lignin modification degree to achieve the optimal balance between dispersion stability and jetting reliability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides stable and reliable inkjet inks with improved storage stability, jetting performance, and enhanced wet crock fastness, ensuring high-quality prints on polyester textiles without compromising image quality or hue.

Implementation Method 1

aqueous inkjet ink composition comprising water, a disperse dye, a dispersant and lignin

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

Improved ink stability is claimed due to the presence of lignin sulfonic acid

Methodology Applied
Scientific EffectStabilization:

Implementation Method 3

The disperse dye penetrates and diffuses into the fibres under high temperature condition

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 4

is fixed by means of hydrogen bond, intermolecular force, etc. between the fibre and the dye

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 5

fixing a colouring material to the fabric by means of steaming or baking treatment after providing the ink composition

Methodology Applied
Scientific EffectHeat treatment: Heating

Implementation Method 6

the dye is sublimated and transferred from a side on the intermediate transfer medium to a recording medium to be dyed

Methodology Applied
Scientific EffectSublimation: Sublimation

Data Source

PatentEP4321582A1Aqueous ink jet composition for textile printing
Publication Date: 2024.02.14 AGFA NV
  • EP4321582A1 patent drawing
  • EP4321582A1 patent drawing

AI summary

Aqueous ink for textile printing comprising a disperse dye, a dispersant and lignin. A manufacturing method of this ink is provided. An inkjet recording method on textile fabric using the aqueous ink comprising a disperse dye, a dispersant and lignin is also provided.