Aqueous Textile Coating Composition for Wash-Durable Evaporative Cooling

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Solution Overview

Problem

Current textile coating compositions based on sulfonated styrenic block copolymers face challenges with solvent handling and disposal, and they lack durability during multiple laundering cycles, leading to a loss of coating performance.

Innovation Solution

Aqueous emulsion of midblock sulfonated styrenic block copolymer combined with poly(vinyl alcohol), applied onto fabrics with heat and optional pressure, to create a coating that withstands at least 50 wash cycles while maintaining evaporative cooling properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If solvent-based coating compositions are used, then the coating provides good initial performance and evaporative cooling effect, but the coating lacks durability and deteriorates after multiple wash cycles

Engineering Contradiction:
Improvecoating durabilityVSAvoidcoating lifespan through wash cycles
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent combines sulfonated styrenic block copolymer (providing evaporative cooling) with poly(vinyl alcohol) (providing durability and wash resistance). This composite coating system allows both functions to coexist: the copolymer maintains cooling performance while the PVA matrix provides structural integrity through multiple wash cycles, resolving the contradiction between initial performance and long-term durability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of the coating by incorporating poly(vinyl alcohol) at specific concentrations (5-50 wt% of total coating solids) and adjusting the ratio of copolymer to PVA. This parameter optimization ensures the coating achieves both the evaporative cooling effect and the durability required to withstand 50+ wash cycles

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If aqueous emulsion is used instead of organic solvent, then environmental friendliness and safety improve, but coating durability and performance retention deteriorate

Engineering Contradiction:
Improveenvironmental impactVSAvoidcoating durability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the solvent parameter from organic to aqueous while compensating for potential performance loss by optimizing the polymer composition and ratios. The specific formulation of sulfonated copolymer with PVA in water maintains both environmental benefits and coating durability, proving that parameter substitution can achieve multiple goals simultaneously

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If poly(vinyl alcohol) is added to enhance wash durability, then coating lifespan through wash cycles improves, but the complexity of the coating formulation increases

Engineering Contradiction:
Improvecoating lifespan through wash cyclesVSAvoidcoating formulation complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent selects poly(vinyl alcohol) as a multi-functional additive that simultaneously provides wash durability, film formation, and compatibility with the sulfonated copolymer. This single material performs multiple functions, reducing the need for additional specialized additives and keeping the overall formulation relatively simple despite the enhanced performance requirements

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a stable and durable coating that retains its enhanced evaporative cooling effect and wash durability, outperforming traditional solvent-based systems by ensuring the coating composition remains intact and functional after extensive washing.

Implementation Method 1

an aqueous emulsion of a midblock sulfonated styrenic block copolymer and a poly(vinyl alcohol)

Methodology Applied
Scientific EffectEmulsion: Emulsion

Implementation Method 2

dissolving the poly(vinyl alcohol) into the emulsion

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 3

applying heat and optionally pressure

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

applying heat and optionally pressure

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 5

the polymer swells and binds with moisture. The moisture may then be released to the environment. It thereby provides an enhanced evaporative cooling effect

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS10047477B2Textile coating composition
Publication Date: 2018.08.14 KRATON POLYMERS US LLC
  • US10047477B2 patent drawing

AI summary

The current invention concerns a textile coating composition comprising an aqueous emulsion of a midblock sulfonated styrenic block copolymer and a poly(vinyl alcohol). It also concerns a method for preparing the textile coating composition and its application. It also concerns fabrics on which the coating compositions have been applied.