Anti-Reflective Coating Silica Nanoparticle Ratio

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Solution Overview

Problem

There is a need for composite films with high visible light transmittance (VLT), low haze values, and low reflectance, particularly for medical glass components and protective shields, where existing solutions do not adequately meet these combined performance criteria.

Innovation Solution

A composite film comprising a transparent substrate with an anti-reflective coating made of a UV curable acrylate binder, a photo initiator component, and silica nanoparticles, with specific concentration ratios and ranges that enhance VLT and reduce haze and reflectance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional anti-reflective coatings are applied to glass substrates, then reflectance is reduced, but visible light transmittance and haze control cannot simultaneously achieve high VLT (>93%) and low haze (<3%)

Engineering Contradiction:
ImprovereflectanceVSAvoidoptical performance consistency
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent uses a composite anti-reflective coating containing silica nanoparticles (5-60 wt%), UV curable acrylate binder (40-95 wt%), and photo initiator (2-10 wt%). This composite formulation achieves simultaneous optimization of reflectance reduction, high visible light transmittance (>93%), and low haze (<3%) that conventional single-material coatings cannot achieve.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes specific parameter ranges: silica nanoparticle concentration (5-60 wt%), binder concentration (40-95 wt%), photo initiator concentration (2-10 wt%), and silica-to-binder ratio (0.05-1.3). These parameter changes enable precise control over optical properties to achieve >93% VLT and <3% haze while maintaining anti-reflective functionality.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If silica nanoparticles are added to anti-reflective coating to reduce haze, then haze value decreases, but visible light transmittance may be compromised

Engineering Contradiction:
Improvehaze controlVSAvoidvisible light transmittance
Core Design Contradiction:
Manufacturing precisionVSIllumination intensity

Solution Approach 1:

The patent identifies optimal silica nanoparticle concentration ranges (5-60 wt%) and silica-to-binder ratios (0.05-1.3) that achieve haze <3% while maintaining VLT >93%. This precise parameter optimization resolves the trade-off between haze reduction and light transmittance preservation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent specifies nanoparticle size distribution (D50: 10-100 nm, D90: 20-200 nm) to ensure nanoparticles are small enough to minimize light scattering (reducing haze) while maintaining sufficient transmittance. This local quality control of particle size achieves simultaneous haze reduction and high VLT.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite film achieves VLT of at least 93% and haze values not greater than 3%, providing improved optical characteristics suitable for medical and protective applications.

Implementation Method 1

The first anti-reflective coating may include a first UV curable acrylate binder, a photo initiator component

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

a first anti-reflective coating overlying a first surface of the first transparent substrate

Methodology Applied
Scientific EffectAnti-reflective coating effect: Anti-Reflective Coating

Data Source

PatentUS11840642B2Composite film with anti-reflective coating
Publication Date: 2023.12.12 SAINT GOBAIN PERFORMANCE PLASTICS CORP
  • US11840642B2 patent drawing
  • US11840642B2 patent drawing
  • US11840642B2 patent drawing

AI summary

A composite film may include a first transparent substrate and a first anti-reflective coating overlying a first surface of the first transparent substrate. The first anti-reflective coating may include a first UV curable acrylate binder, a photo initiator component, and silica nanoparticles dispersed within the first anti-reflective coating. The first anti-reflective coating may further include a ratio AC1SiO2/AC1B of at least about 0.01 and not greater than about 1.3. The composite film may further have a VLT of at least about 93.0% and a haze value of not greater than about 3%.