Aramid Fiber Surface Treatment for Stronger Elastomer Bonding

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Solution Overview

Problem

Aramid fibers exhibit poor adhesion to elastomer materials due to their high crystallinity and smooth surface, leading to inadequate reinforcement and durability in products like tires and belts, which can limit their applications.

Innovation Solution

The surface of aramid fibers is modified through acid treatment, microwave irradiation, mechanical bending, and the use of coupling agents to increase roughness and adhesion, involving steps such as immersion in acid solutions, microwave exposure, and application of tensile forces to create a textured surface that enhances bonding with elastomers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If aramid fibers are used as reinforcement elements, then strength and durability are improved, but adhesion to elastomer materials deteriorates due to high crystallinity and smooth surface

Engineering Contradiction:
Improvestrength and durabilityVSAvoidadhesion to elastomer
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The aramid fibers undergo preliminary surface treatment with acid solution and microwave irradiation before being incorporated into elastomer products. This pre-treatment modifies the fiber surface to enhance adhesion, ensuring reliable bonding before the final product assembly and use.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The surface properties of aramid fibers are modified by changing physical and chemical parameters through acid treatment and microwave irradiation. This alters the surface energy, roughness, and chemical reactivity of the fibers, transforming them from having poor adhesion to exhibiting enhanced adhesion to elastomer materials.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If surface modification treatments are applied to improve adhesion, then adhesion strength is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveadhesion to elastomerVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

Multiple surface modification steps (acid treatment, microwave irradiation, mechanical bending, coupling agent application) are merged into a single integrated treatment process. This combination achieves comprehensive surface modification with enhanced adhesion while streamlining the manufacturing workflow.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

Traditional mechanical surface treatment methods are replaced with microwave irradiation, which uses electromagnetic energy to modify the fiber surface. This substitution reduces mechanical complexity and enables more uniform and controlled surface modification.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modified aramid fibers demonstrate improved adhesion to elastomer materials, with adhesion strengths exceeding 0.8 MPa, effectively addressing the limitations of untreated fibers and enhancing the mechanical properties of elastomer products.

Implementation Method 1

contacting the aramid fiber with an acid solution for a pre-determined amount of time to form a pre-treated aramid fiber

Methodology Applied
Scientific EffectChemical etching: Ablation

Implementation Method 2

irradiating the pre-treated aramid fiber in the liquid to modify the surface of the aramid fiber

Methodology Applied
Scientific EffectMicrowave heating: Dielectric Heating

Implementation Method 3

removing the aramid fiber of step (a) from the acid solution and immersing the pre-treated aramid fiber in a liquid

Methodology Applied
Scientific EffectHeat transfer: Convection

Data Source

PatentUS12065777B2Methods for modification of aramid fibers
Publication Date: 2024.08.20 BRIDGESTONE CORP
  • US12065777B2 patent drawing
  • US12065777B2 patent drawing
  • US12065777B2 patent drawing

AI summary

Methods are described for treatment of aramid fibers to modify the surface of the fibers. The treated fibers have improved adhesion to elastomer materials as compared to untreated fibers. Modification methods include irradiating the fibers, compressing and straining the fibers under a constant pull force and immersing the fibers in a coupling agent fluid. The treated fibers can be used with elastomers and provide reinforcement elements in products such as tires.