Aromatic Lactam Matrix Materials for Phosphorescent OLEDs

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current organic electroluminescent devices (OLEDs) face challenges in efficiency, operating voltage, and lifetime, particularly for phosphorescent OLEDs, where the materials used beyond triplet emitters, such as matrix materials, require improvement to enhance overall device performance.

Innovation Solution

Development of specific compounds with defined structural formulas and properties, including aromatic and heteroaromatic ring systems, which serve as suitable matrix materials or electron transport materials, leading to improved OLED properties like long lifetime, high efficiency, and low operating voltage when used in OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If conventional matrix materials are used in phosphorescent OLEDs, then device structure is simple, but lifetime is short and efficiency is low

Engineering Contradiction:
ImproveOLED lifetimeVSAvoidmaterial structure complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent employs composite materials by combining specific aromatic lactam core structures with various aromatic or heteroaromatic substituent groups. This composite approach creates matrix materials with optimized properties for phosphorescent OLEDs, achieving extended lifetime and improved efficiency while maintaining reasonable structural complexity through systematic molecular design

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional matrix materials are used in phosphorescent OLEDs, then manufacturing is simple, but efficiency is low

Engineering Contradiction:
ImproveOLED efficiencyVSAvoidmaterial structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent systematically varies key molecular parameters including the core lactam structure (formula I), substituent types (formula R), and aromatic ring systems to optimize material properties. This parameter optimization approach enhances OLED efficiency by tuning energy levels, charge transport characteristics, and triplet energy states while maintaining manageable structural complexity

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If conventional materials are used in OLEDs, then operating voltage is high, but material selection is simple

Engineering Contradiction:
Improveoperating voltageVSAvoidmaterial structure complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent optimizes operating voltage by adjusting molecular parameters of the matrix materials, including HOMO/LUMO energy levels and charge mobility characteristics. The systematic variation of aromatic substituents and lactam core structures enables tuning of electrical properties to reduce operating voltage while maintaining structural feasibility

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS20230292596A1Materials for organic electroluminescent devices
Publication Date: 2023.09.14 MERCK PATENT GMBH
  • US20230292596A1 patent drawing
  • US20230292596A1 patent drawing
  • US20230292596A1 patent drawing

AI summary

The present invention relates to compounds which are suitable for use in electronic devices, and to electronic devices, in particular organic electroluminescent devices, containing said compounds.