Array Substrate Passivation via Aluminum Oxidation for TFT Reliability

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Solution Overview

Problem

Current methods for preparing aluminum oxide passivation layers in thin film transistor devices are inadequate for large-size production due to the brittleness of alumina targets and the high hydrogen content in silicon nitride films, which affects the performance of thin film transistors.

Innovation Solution

A method involving the deposition of a first passivation layer, an original metal layer, and an oxygen source layer on a substrate, followed by heat treatment to form a double-layer passivation structure, where the original metal layer is oxidized and the oxygen source layer is deoxidized, facilitating the formation of a large-size metal oxide passivation layer with improved water and oxygen blocking capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If physical sputtering method is used to prepare aluminum oxide passivation layer, then the passivation layer can be formed, but the alumina target is brittle and difficult to make for large-size deposition

Engineering Contradiction:
Improveease of preparing passivation layerVSAvoidsize of passivation layer
Core Design Contradiction:
Ease of manufactureVSArea of stationary object

Solution Approach 1:

The passivation layer preparation is divided into two separate steps: first forming a metal layer (e.g., aluminum), then oxidizing it in a subsequent oxidation step. This segmentation allows the metal layer to be deposited using conventional sputtering with standard metal targets, avoiding the brittleness issue of large-size alumina targets while still achieving the desired aluminum oxide passivation layer.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The metal layer is prepared in advance through physical sputtering, and then the oxidation is performed as a preliminary action in a separate step. This preliminary formation of the metal layer allows using stable, non-brittle metal targets rather than fragile ceramic alumina targets, enabling large-size deposition.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If silicon nitride is used to make passivation layer, then water vapor isolation ability is improved, but hydrogen content becomes too high and deteriorates thin film transistor performance

Engineering Contradiction:
Improvewater vapor isolation abilityVSAvoidhydrogen content in channel layer
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention changes the material parameter from silicon nitride to aluminum oxide (formed by oxidizing aluminum layer). Aluminum oxide provides comparable or better water vapor isolation ability while eliminating the hydrogen incorporation problem associated with silicon nitride deposition using silane and ammonia gases.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If silicon dioxide is used to make passivation layer, then the passivation layer can be formed easily, but water vapor isolation ability is poor

Engineering Contradiction:
Improveease of preparing passivation layerVSAvoidwater vapor isolation ability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention changes the material parameter from silicon dioxide to aluminum oxide. While silicon dioxide is easier to deposit, aluminum oxide provides superior water vapor isolation properties. The oxidation step converts the easily-deposited aluminum metal layer into aluminum oxide, achieving both ease of manufacture and high reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the easy production of a large-size metal oxide passivation layer with a double-layer structure, enhancing the ability to isolate water and oxygen, thus improving the performance and durability of thin film transistors.

Implementation Method 1

heat-treating the oxygen source layer and the original metal layer, wherein the original metal layer is oxidized to form a second passivation layer

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

performing a heat treatment on the oxygen source layer and the original metal layer over a preset duration at a preset temperature

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 3

the oxygen source layer is deoxidized to form a deoxidation layer

Methodology Applied
Scientific EffectDeoxidation: Reduction

Implementation Method 4

depositing the original metal layer of a first thickness on the first passivation layer by a physical deposition process

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS20230395616A1Method of manufacturing array substrate, array substrate, and display device
Publication Date: 2023.12.07 SHENZHEN CHINA STAR OPTOELECTRONICS SEMICON DISPLAY TECH CO LTD
  • US20230395616A1 patent drawing
  • US20230395616A1 patent drawing
  • US20230395616A1 patent drawing

AI summary

The present disclosure provides a method of manufacturing an array substrate, the array substrate, and a display device. The method of manufacturing the array substrate includes: a step of preparing a substrate; a step of preparing a driving circuit layer on the substrate; a step of preparing a first passivation layer on the driving circuit layer; a step of preparing an original metal layer on the first passivation layer; a step of preparing an oxygen source layer on the original metal layer; a step of heat-treating the oxygen source layer and the original metal layer, wherein the original metal layer is oxidized to form a second passivation layer.