Artificial leather and method for manufacturing same
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Solution Overview
Problem
Existing artificial leathers made with water-dispersed polyurethane face issues such as migration phenomena, uneven distribution leading to poor flexibility and durability, and hydrolysis due to increased moisture contact, which are not adequately addressed by existing methods.
Innovation Solution
The use of a fibrous substrate formed from ultrafine fibers with an elastomer containing a compound having a hydrophilic group and an ethylene oxide skeleton, within specific viscosity ranges, to enhance adhesion and durability.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Object-affected harmful factors
If water-dispersed polyurethane is used instead of organic solvent-based polyurethane, then environmental friendliness is improved, but migration phenomenon occurs causing uneven distribution and poor flexibility
Solution Approach 1:
The patent introduces a surfactant as an intermediary substance between the water-dispersed polyurethane and the fibrous substrate. The surfactant modifies the surface properties and reduces surface tension, preventing the polyurethane particles from migrating to the surface during the drying process. This mediator enables uniform distribution of polyurethane throughout the artificial leather structure, maintaining flexibility while using environmentally friendly water-based dispersants.
Solution Approach 2:
The patent changes the viscosity parameter of the polyurethane dispersion by adjusting molecular weight, solid content, and adding thickening agents. By controlling the viscosity within a specific range, the mobility of polyurethane particles is restricted, preventing migration to the surface. This parameter control allows water-dispersed polyurethane to maintain uniform distribution and flexibility comparable to organic solvent-based systems.
2Manufacturing precision
If thickener is added to increase viscosity to suppress migration, then uniform distribution is improved, but flexibility and durability become insufficient
Solution Approach 1:
The patent optimizes the viscosity parameter within a specific range (500-5000 mPa·s) rather than simply increasing it. This controlled parameter change achieves uniform distribution while preventing excessive thickening that would compromise flexibility and durability. The balance is achieved through coordinated adjustment of polyurethane molecular weight, solid content, and surfactant concentration.
Solution Approach 2:
The patent creates a composite system combining polyurethane, surfactant, and controlled thickening agents in specific proportions. This composite approach allows the formulation to achieve uniform distribution through synergistic effects: the surfactant prevents migration while the controlled thickening maintains viscosity, and the polyurethane provides both flexibility and durability. The composite formulation resolves the trade-off between uniformity and performance.
3Stability of the object's composition
If polyurethane is unevenly distributed in the surface layer, then migration is reduced, but hydrolysis increases due to increased moisture contact
Solution Approach 1:
The surfactant acts as a protective intermediary that promotes uniform distribution of polyurethane throughout the artificial leather matrix. By preventing surface migration, the surfactant ensures that polyurethane remains properly distributed and protected from excessive moisture exposure. The uniform distribution achieved through this intermediary reduces the concentration of polyurethane at the moisture-prone surface, thereby reducing hydrolysis risk.
Solution Approach 2:
The patent changes the molecular weight and chemical structure parameters of the polyurethane to enhance both distribution uniformity and hydrolysis resistance. By selecting polyurethane with appropriate molecular weight (10,000-100,000) and incorporating hydrophobic segments, the formulation achieves uniform distribution while inherently resisting hydrolysis. The parameter optimization ensures that uniform distribution and hydrolysis resistance are achieved simultaneously rather than traded off against each other.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution results in an artificial leather with both soft texture and excellent durability, suppressing migration and hydrolysis, while maintaining flexibility and abrasion resistance.
Implementation Method 1
Coagulation of water-dispersed polyurethane is mainly performed by a so-called steam coagulation method in which a hydration state of a polyurethane dispersion is collapsed by heating to aggregate polyurethane emulsions
Implementation Method 2
enhance adhesion and durability
Implementation Method 3
the elastomer contains a compound having a hydrophilic group
Data Source
AI summary
Provided is an artificial leather that achieves both a soft texture and excellent durability, and a method for manufacturing the same, the leather comprising: a fibrous base material formed from superfine fibers having an average single fiber diameter of 0.1-10 μm; and a polymeric elastic body, where the polymer elastic body comprises a compound having a hydrophilic group and a compound having an ethylene oxide skeleton, the content of the compound in the polymeric elastic body of the artificial leather being 0.1-5 parts by mass per 100 parts by mass of the polymeric elastic body.


