Asphalt Modifier Package Storage Stability

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Solution Overview

Problem

Asphalt-modified with Ground Tire Rubber (GTR) faces challenges in storage stability due to particle settling, especially at elevated temperatures, and existing solutions are costly and introduce undesirable qualities like causticity.

Innovation Solution

An asphalt modifier package comprising GTR, an amine functionalized wax, and an elastomeric polymer, where GTR can have larger particle sizes and the amine functionalized wax encourages interaction with asphalt components to prevent settling, improving storage stability and physical characteristics without introducing causticity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If GTR particles are made extremely small (140 mesh or smaller) to prevent settling, then storage stability improves, but manufacturing cost increases significantly

Engineering Contradiction:
Improvestorage stabilityVSAvoidmanufacturing cost
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent introduces an intermediary substance (asphalt binder with specific chemical composition and viscosity characteristics) that mediates between the GTR particles and prevents their settling without requiring extreme particle size reduction. The binder acts as a stabilizing medium that maintains GTR particles in suspension through appropriate rheological properties and chemical interactions.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the parameter of GTR particle size from extremely small (140 mesh or smaller) to a broader range including larger particles, while compensating by adjusting other parameters of the asphalt binder (chemical composition, viscosity, temperature range) to maintain storage stability without the need for excessive particle fineness.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If additional additives (inorganic or organic acids) are used to prevent GTR settling, then storage stability improves, but cost increases and undesirable caustic action is introduced

Engineering Contradiction:
Improvestorage stabilityVSAvoidcaustic action
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent converts the potential harm of caustic additives into a benefit by using the natural chemical composition of asphalt binder (which contains natural acids and resins) to achieve the same stabilizing effect without introducing external caustic substances. The asphalt's inherent chemical properties are utilized to prevent GTR settling while avoiding the harmful effects of added acidic additives.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The asphalt binder serves itself by utilizing its own chemical composition and rheological properties to prevent GTR particle settling, rather than requiring external additives. The binder's natural acids, resins, and viscosity characteristics provide the stabilizing function that would otherwise require additional costly and potentially harmful additives.

Inventive Principle:
Principle #25Self-service

3Stability of the object's composition

If continuous mixing is implemented to prevent GTR settling, then storage stability improves, but energy consumption and operational complexity increase

Engineering Contradiction:
Improvestorage stabilityVSAvoidenergy consumption
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by stationary object

Solution Approach 1:

The patent applies preliminary action by properly formulating the asphalt binder with appropriate chemical composition and viscosity characteristics before mixing with GTR particles. This pre-prepared binder composition provides inherent stability that prevents settling during storage and transport, eliminating the need for continuous mixing operations and reducing energy consumption.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modifier package achieves excellent storage stability and physical properties, such as reduced rutting and deformation resistance, at a low add-in level, without the need for small GTR particle sizes or costly additives, ensuring stability and performance in asphalt applications.

Implementation Method 1

the amine functionalized wax encourages interaction with asphalt components to prevent settling

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 2

The elastomeric polymer can include a reactive elastomeric terpolymer (RET)... improving storage stability and physical characteristics

Methodology Applied
Scientific EffectElasticity: Elasticity

Data Source

PatentUS20220135802A1Asphalt modifier composition and rubber-modified asphalt having increased storage stability
Publication Date: 2022.05.05 LIBERTY TIRE RECYCLING LLC
  • US20220135802A1 patent drawing
  • US20220135802A1 patent drawing

AI summary

Asphalt modifier packages and rubber-modified asphalts including the packages are described. Asphalt modifier packages can include an amine functionalized wax and an elastomeric polymer in conjunction with ground tire rubber. Asphalt modifiers can include a ground tire rubber compounded with a reactive elastomeric terpolymer. Rubber-modified asphalts can exhibit an excellent stability of the ground tire rubber additive. Rubber-modified asphalts can exhibit a storage stability separation factor of about 6° F. or less, an MSCR Jnr value of from about 0.05 to about 2 at 3.2 kPa and 67° C., and an MSCR percent recovery of from about 20% to about 75% at 3.2 kPa and 67° C.