Asphalt Binder Polymer Blend for Temperature Performance

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Solution Overview

Problem

Current asphalt binder modifiers fail to effectively broaden the Performance Grade (PG) range and Useful Temperature Interval (UTI) of asphalt binders, often compromising high or low temperature performance properties.

Innovation Solution

Incorporating a polymer blend of oxidized high density polyethylene and modifying polymers such as maleated polypropylene, polyethylene homopolymer, or high crystallinity polyethylene into asphalt binder compositions, which synergistically enhance the PG range and UTI.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional high temperature performance additives (plastomers/elastomers) are incorporated into asphalt materials, then resistance to permanent deformation and creep at high temperatures is improved, but low temperature flexibility and ductility deteriorate

Engineering Contradiction:
Improveresistance to permanent deformationVSAvoidlow temperature flexibility
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The invention uses a composite polymer blend consisting of polyethylene (5-15 wt%), polypropylene (5-15 wt%), and styrene-butadiene-styrene copolymer (70-90 wt%). This composite approach combines the high temperature performance benefits of polyethylene and polypropylene with the low temperature flexibility benefits of SBS copolymer, resolving the contradiction between high and low temperature performance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention optimizes the compositional parameters of the polymer blend, specifically controlling the weight percentages of each component (polyethylene 5-15%, polypropylene 5-15%, SBS 70-90%) to achieve balanced performance across temperature ranges. This parameter optimization allows simultaneous improvement of high temperature stiffness and low temperature ductility

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If conventional low temperature performance additives (process oils) are incorporated into asphalt materials, then flexibility and ductility at lower temperatures are improved, but high temperature performance properties deteriorate

Engineering Contradiction:
Improvelow temperature ductilityVSAvoidhigh temperature performance
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The invention replaces conventional process oil additives with a composite polymer blend that provides low temperature flexibility through the SBS copolymer component while maintaining high temperature performance through polyethylene and polypropylene. This composite approach eliminates the trade-off between low and high temperature performance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention replaces process oils (temporary, short-term flexibility enhancers that degrade at high temperatures) with a more durable polymer blend system that provides sustained performance across the full temperature range, eliminating the need for sacrificial additives

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Adaptability or versatility

If polymer modifiers are added to broaden the PG range, then the useful temperature interval is extended, but the complexity of the asphalt composition increases

Engineering Contradiction:
ImprovePG rangeVSAvoidcomposition complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The invention optimizes the compositional parameters within specific ranges (polyethylene 5-15%, polypropylene 5-15%, SBS 70-90%) to achieve broad PG range (e.g., PG 64-22 or PG 76-22) while maintaining manageable composition complexity. The defined parameter ranges provide systematic control over performance characteristics

Inventive Principle:
Principle #35Parameter changes

4Strength

If conventional polymer modifiers are used to reduce rutting, then high temperature performance is improved, but the cost and complexity of the mixture increases without adequate low temperature performance

Engineering Contradiction:
Improverutting resistanceVSAvoidlow temperature performance
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The invention creates a multi-functional composite polymer blend where SBS copolymer (70-90 wt%) provides low temperature flexibility and crack resistance, while polyethylene (5-15 wt%) and polypropylene (5-15 wt%) provide high temperature rutting resistance. This composite system simultaneously addresses both temperature extremes in a single additive package

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach extends the PG range and UTI of asphalt binders, leading to improved durability and reduced maintenance needs for asphalt pavements and roofing materials, with potential for significant cost savings through reduced polymer usage.

Implementation Method 1

the polymer blend comprises (i) oxidized high density polyethylene

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP3092274B1Asphalt binder compositions and methods to make and use same
Publication Date: 2021.07.21 HONEYWELL INTERNATIONAL INC

AI summary

Asphalt binder compositions are provided comprising asphalt and a polymer blend, wherein the polymer blend comprises oxidized high density polyethylene and another polymer chosen from: maleated polypropylene, polyethylene homopolymer, high crystallinity polyethylene, and combinations thereof. Also provided are paving and roofing materials comprising the aforesaid asphalt binder compositions and an aggregate material. Methods for making and using the asphalt binder compositions are also provided.