Asphalt Viscosity and Low Temperature Performance via Wax

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Solution Overview

Problem

Asphalt compositions face challenges in maintaining optimal properties across various temperature ranges, with petroleum waxes typically leading to stiffening and embrittlement at low temperatures, and conventional methods failing to improve both high and low temperature performance simultaneously.

Innovation Solution

The method involves fractionating a mineral crude oil feedstock to form an asphalt fraction and mixing it with a pour point depressant and refinery wax, with the pour point depressant being less than 10 wt% of the wax content, to create an asphalt product that can be stored and mixed at lower temperatures while improving low temperature properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If petroleum wax is added to asphalt, then high temperature viscosity is reduced, but low temperature performance deteriorates due to stiffening and embrittlement

Engineering Contradiction:
Improvehigh temperature viscosityVSAvoidlow temperature performance
Core Design Contradiction:
TemperatureVSStrength

Solution Approach 1:

The patent converts the harmful effect of wax crystallization at low temperatures into a beneficial effect by using pour point depressants to modify the crystal structure. Instead of preventing wax addition entirely, the invention uses the wax's natural tendency to crystallize and transforms it into a controlled structure that provides high temperature viscosity reduction while maintaining low temperature flexibility through modified crystal morphology.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent introduces pour point depressants as intermediary substances that mediate between the wax and the asphalt matrix. These additives act as mediators that interact with wax crystals during formation, modifying their structure and preventing the harmful stiffening effect while preserving the beneficial viscosity reduction at high temperatures.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If conventional fractionation is used to produce asphalt, then production efficiency is maintained, but both high and low temperature performance cannot be improved simultaneously

Engineering Contradiction:
Improveproduction efficiencyVSAvoidtemperature range performance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent merges multiple functions into a single integrated process: fractionation to separate asphalt from feedstock, simultaneous addition of pour point depressants, and controlled wax crystallization all occur in one continuous process. This combines production efficiency with performance improvement by eliminating separate processing steps while achieving both high and low temperature performance goals.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent changes key process parameters including fractionation cut points, additif dosing rates, and cooling rates to control wax crystallization. By adjusting these parameters, the process achieves optimal balance between production efficiency and asphalt performance across the temperature range, producing asphalt that meets both productivity requirements and performance specifications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the viscosity of asphalt at higher temperatures, allows for reduced storage and mixing temperatures, and enhances low temperature performance, enabling the use of asphalt in a wider range of applications and extending the paving season while reducing energy usage and emissions.

Implementation Method 1

mixing the asphalt fraction with a pour point depressant to form an asphalt product

Methodology Applied
Scientific EffectPour point depression: Phase Change

Implementation Method 2

fractionating a feedstock containing at least a portion derived from a mineral crude oil at a cut point of at least 750° F. (399° C.) to form an asphalt fraction

Methodology Applied
Scientific EffectFractionation: Distillation

Implementation Method 3

dewaxing at least a portion of the one or more vacuum gas oil fractions under effective solvent dewaxing conditions to form a dewaxed vacuum gas oil and a refinery wax product

Methodology Applied
Scientific EffectSolvent dewaxing: Solvation

Data Source

PatentUS9068129B2Upgrading properties of asphalts with wax
Publication Date: 2015.06.30 EXXONMOBIL TECHNOLOGY & ENGINEERING CO
  • US9068129B2 patent drawing
  • US9068129B2 patent drawing
  • US9068129B2 patent drawing

AI summary

Methods are provided for upgrading the quality of an asphalt containing wax. This can include base asphalts that naturally contain elevated levels of wax, such as base asphalts with a wax content of at least 3.0 wt %. Additionally or alternately, this can include a base asphalt containing subsequently added wax. Wax generated at a refinery can be added to an asphalt along with a pour point depressant to form an asphalt product. The additional wax can reduce the viscosity of the asphalt product at higher temperatures so that the asphalt product can be mixed and stored at a tower temperature. Additionally, the pour point depressant can unexpectedly improve the low temperature properties of the wax-containing asphalt product.