Asphaltene Dispersant Composition for Marine Diesel Engine Cleanliness

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Solution Overview

Problem

Lubricating oils for medium or low speed diesel engines, particularly marine diesel engines, face contamination issues with unburned residual fuel oil leading to severe engine cleanliness problems known as 'black paint' or asphaltene deposits, which affect detergency and engine performance.

Innovation Solution

A lubricating composition comprising an oil of lubricating viscosity, an asphaltene dispersant with an amide group, and a detergent derived from an alkyl phenol, where the asphaltene dispersant includes a succinimide group and may also contain a nitrogen-containing cyclic headgroup, effectively addressing asphaltene and 'black paint' deposit issues without compromising detergency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional lubricating oil compositions are used, then lubricating performance is maintained, but severe asphaltene and 'black paint' deposits occur in the engine

Engineering Contradiction:
Improveasphaltene depositsVSAvoidengine cleanliness
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent converts the harmful effect of unburned residual fuel oil and asphaltene precursors into a beneficial outcome by using specifically designed dispersants that transform these contaminants into stable, suspended particles that prevent deposit formation. The dispersants convert the harmful asphaltene aggregation tendency into a controlled suspension state that protects engine surfaces.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent introduces asphaltene dispersants as intermediary substances that mediate between the harmful unburned fuel residues and the engine surfaces. These dispersants act as protective intermediaries that prevent direct contact between asphaltene deposits and engine surfaces, thereby maintaining engine cleanliness while allowing the use of residual fuel oil.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If dispersants are added to reduce asphaltene deposits, then engine cleanliness improves, but detergency performance may be compromised

Engineering Contradiction:
Improveasphaltene depositsVSAvoiddetergency
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent achieves multi-functionality by designing dispersant compositions that simultaneously provide both asphaltene dispersion and detergency functions. The composition includes multiple components that work together: some specifically target asphaltene particles while others maintain general detergency, creating a universal additive system that addresses multiple contamination issues without compromise.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent uses composite additive compositions that combine multiple dispersant and detergent components with different specific functions. This composite approach allows the formulation to address both asphaltene deposits and general detergency requirements through synergistic interaction of the various components, rather than relying on a single additive type.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition significantly reduces asphaltene and 'black paint' deposits, maintaining overall lubricating performance and detergency in marine diesel engines, thereby improving engine cleanliness and reducing cylinder wear.

Implementation Method 1

an asphaltene dispersant comprising an amide group... the asphaltene dispersant includes a succinimide group

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

an oil of lubricating viscosity... maintaining overall lubricating performance

Methodology Applied
Scientific EffectLubrication: Lubrication

Data Source

PatentEP2673347B1Asphaltene dispersant containing lubricating compositions
Publication Date: 2018.09.12 THE LUBRIZOL CORP
  • EP2673347B1 patent drawing
  • EP2673347B1 patent drawing
  • EP2673347B1 patent drawing

AI summary

The present invention relates to a lubricating composition, particularly marine diesel engine lubricating compositions, comprising: (a) an oil of lubricating viscosity; (b) an asphaltene dispersant comprising an amide group, which may also contain a succinimide group, and which may optionally be used in combination with additional asphaltene dispersants that contain a cyclic headgroup that contains a nitrogen atoms where the additional asphaltene dispersants may also include a succinimide group; and (c) a detergent derived from an alkyl phenol. The invention further provides methods of using such compositions in the operation of engine, particularly marine diesel engines.