Asymmetric Cyclic Deposition Etch for Source Drain Resistivity

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Solution Overview

Problem

Existing methods for forming source and drain regions in semiconductor devices, such as CMOS transistors, face challenges in achieving low resistivity and sufficient carbon concentration while maintaining high throughput due to limitations in etching rates and dopant activation levels, particularly at advanced technology nodes.

Innovation Solution

The implementation of an asymmetric cyclic deposition and etch (ACDE) process using Cl2 as an etchant, which differs from traditional methods by incorporating a preparation layer of carbon-doped silicon and subsequent phosphorus soaking to enhance epitaxial growth, allowing for higher dopant incorporation and reduced etching time, thereby achieving lower resistivity and sufficient carbon concentration in the silicon-containing material.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional etching methods are used, then etching process is simpler, but etching rate is lower and etching time is longer

Engineering Contradiction:
Improveetching rateVSAvoidetching process complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The etching process is divided into multiple cyclic steps including deposition of silicon-containing material, etching with Cl2, and conditional repetition based on thickness measurements. This segmentation enables precise control of etching rate and depth while maintaining process simplicity through automation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent implements periodic cyclic deposition and etching actions where silicon-containing material is deposited and then etched in repeating cycles. This periodic action achieves high etching rates while maintaining precision through the rhythmic alternation of deposition and removal phases.

Inventive Principle:
Principle #19Periodic action

2Reliability

If higher dopant concentration is achieved, then resistivity decreases, but carbon concentration control becomes more difficult

Engineering Contradiction:
ImproveresistivityVSAvoidcarbon concentration uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent employs feedback control by measuring the thickness of the silicon-containing material layer after each cycle and comparing it to a target thickness. The process automatically adjusts by repeating or terminating cycles based on this feedback, ensuring precise carbon concentration control while achieving desired dopant levels and low resistivity.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent changes process parameters including Cl2 flow rate, deposition temperature, and cycle repetition based on real-time thickness measurements. These parameter adjustments enable simultaneous optimization of dopant incorporation and carbon concentration uniformity, achieving low resistivity with precise compositional control.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If epitaxial growth is enhanced, then dopant incorporation increases, but process time increases

Engineering Contradiction:
Improvedopant incorporationVSAvoidprocess time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The patent maintains continuous useful action by performing deposition and etching in tight cyclic sequences without significant idle time. This continuous process enhances dopant incorporation efficiency while minimizing total process time, as each cycle immediately follows the previous one with automated transitions.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent applies partial etching actions where only portions of the deposited material are removed in each cycle, allowing dopant incorporation to occur during deposition while limiting time-consuming etching to what is necessary for thickness control. This partial action approach optimizes the balance between dopant incorporation and process time.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in source and drain regions with lower resistivity and higher carbon concentration, meeting the demands of advanced technology nodes by improving throughput and maintaining process control, while ensuring sufficient dopant activation and uniformity.

Implementation Method 1

depositing an epitaxial silicon-containing layer in the recesses, wherein the depositing of the epitaxial silicon-containing layer uses an asymmetric cyclic deposition and etching (ACDE) process

Methodology Applied
Scientific EffectEpitaxial growth: Epitaxy

Implementation Method 2

depositing an epitaxial silicon-containing layer in the recesses, wherein the depositing of the epitaxial silicon-containing layer uses an asymmetric cyclic deposition and etching (ACDE) process

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 3

The ACDE process uses Cl2 an etchant

Methodology Applied
Scientific EffectChemical etching:

Implementation Method 4

incorporating a preparation layer of carbon-doped silicon and subsequent phosphorus soaking to enhance epitaxial growth, allowing for higher dopant incorporation

Methodology Applied
Scientific EffectDoping: Dopants

Implementation Method 5

incorporating a preparation layer of carbon-doped silicon and subsequent phosphorus soaking to enhance epitaxial growth, allowing for higher dopant incorporation

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS9093468B2Asymmetric cyclic depositon and etch process for epitaxial formation mechanisms of source and drain regions
Publication Date: 2015.07.28 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US9093468B2 patent drawing
  • US9093468B2 patent drawing
  • US9093468B2 patent drawing

AI summary

The embodiments of mechanisms for forming source/drain (S/D) regions of field effect transistors (FETs) described uses Cl2 as an etchant during the epitaxial formation of the S/D regions. The mechanisms involve using an asymmetric cyclic deposition and etch (ACDE) process that forms a preparation layer enable epitaxial growth of the following epitaxial layer with transistor dopants. The mechanisms also involve soaking the surface of substrate with dopant-containing precursors to enable sufficient incorporation of transistor dopants during the epitaxial growth of the S/D regions. By using Cl2 as etchants, the mechanisms also enables high throughput of the epitaxial growth of the S/D regions.