Asymmetric Transparent Conductive Layer for Solar Cell Light Scattering

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Solution Overview

Problem

Conventional solar cells with transparent conductive oxide front electrodes have a rough surface that scatters incident sunlight, reducing the optical path length in the active layer and limiting the efficiency of solar energy conversion.

Innovation Solution

A transparent conductive layer structure comprising a first textured layer with wave crests and troughs, and a second layer with asymmetric thickness on the inclined planes of the first layer, formed using glancing angle deposition to enhance optical haze and photon path length, improving light scattering and carrier transportation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a rough surface TCO front electrode is used to scatter incident sunlight, then light path in active layer is increased, but optical haze is reduced and photo-electron conversion efficiency is limited

Engineering Contradiction:
Improvephoto-electron conversion efficiencyVSAvoidoptical haze
Core Design Contradiction:
ProductivityVSIllumination intensity

Solution Approach 1:

The patent applies asymmetry by creating a multi-layer transparent conductive structure where the second and third TCO layers have different thicknesses (t2 ≠ t3). This asymmetric thickness distribution on the inclined planes of the textured first layer generates enhanced optical haze through controlled light scattering, while maintaining improved photo-electron conversion efficiency by optimizing the light path length in the active layer.

Inventive Principle:
Principle #4Asymmetry

2Productivity

If a textured structure with wave crests and troughs is created, then light scattering is enhanced, but manufacturing complexity increases

Engineering Contradiction:
Improvelight scattering efficiencyVSAvoidtextured structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent segments the front electrode into multiple TCO layers (first, second, and third layers) with distinct functions. The first layer provides the textured structure for light scattering, while the second and third layers with asymmetric thicknesses optimize optical haze. This segmentation allows each layer to be optimized independently, managing manufacturing complexity while achieving enhanced light scattering efficiency.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The structure significantly increases optical haze and photo-electron conversion efficiency, enhancing the performance of solar cells by increasing the optical path length and improving carrier transportation.

Implementation Method 1

A TCO having a rough surface can scatter incident sunlight and thus increase light path of photons in an active layer of a solar cell

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 2

formed using glancing angle deposition to enhance optical haze and photon path length

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS8710357B2Transparent conductive structure
Publication Date: 2014.04.29 IND TECH RES INST
  • US8710357B2 patent drawing
  • US8710357B2 patent drawing
  • US8710357B2 patent drawing

AI summary

A transparent conductive structure is disclosed, including a first transparent conductive layer and a second transparent conductive layer on the first transparent conductive layer, wherein the first transparent conductive layer has a textured structure including wave crests and wave troughs and the second layer has an asymmetric thickness on inclined planes of the wave crests or the wave troughs of the first transparent conductive layer.