Aluminium Trihydroxide Particle Segmentation for Thermal Conductivity

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Solution Overview

Problem

There is a need for aluminium trihydroxide (ATH) compositions that maintain beneficial thermal conductivity and viscosity properties while replacing or partially replacing existing ATH compositions, with a focus on achieving similar physical properties and improved performance in polymer matrices.

Innovation Solution

The development of an ATH composition comprising a combination of ground aluminium trihydroxide particles with specific size distributions and ratios, including a first plurality of particles with a maximum dimension of 50 to 500 μm and a second plurality of particles with a maximum dimension of less than 50 μm, mixed to achieve a homogeneous particle distribution and optimal thermal conductivity and viscosity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a single particle size of ATH is used, then the composition is simple to manufacture, but the thermal conductivity and viscosity properties are suboptimal

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidthermal conductivity and viscosity properties
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The ATH composition is segmented into multiple particle size fractions: fine particles (5-20 μm), intermediate particles (20-50 μm), and coarse particles (50-100 μm). This segmentation allows each size fraction to contribute differently to the overall performance, with fine particles filling voids and intermediate/coarse particles providing structural framework and thermal conductivity pathways.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different particle size regions within the composition serve different functional qualities. The fine particles (5-20 μm) primarily address viscosity and void filling, the intermediate particles (20-50 μm) balance flow and thermal properties, and the coarse particles (50-100 μm) provide dominant thermal conductivity. This local quality differentiation optimizes both manufacturing ease and performance reliability.

Inventive Principle:
Principle #3Local quality

2Reliability

If ATH particles with larger maximum dimension are used, then thermal conductivity is improved, but viscosity and flow properties deteriorate

Engineering Contradiction:
Improvethermal conductivityVSAvoidviscosity and flow properties
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The particle size distribution is segmented into three distinct ranges with specific weight percentages: 20-40% fine particles (5-20 μm) for flow, 30-50% intermediate particles (20-50 μm) for balance, and 20-40% coarse particles (50-100 μm) for thermal conductivity. This segmentation resolves the contradiction by assigning different size ranges to different functional priorities.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the particle size parameter from a single value to a distributed range with controlled proportions. By adjusting the maximum dimension of coarse particles to 100 μm or less while maintaining a multimodal distribution, the composition achieves optimal balance between thermal conductivity (enhanced by larger particles) and viscosity (maintained by fine particle lubrication).

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If ATH particles with smaller maximum dimension are used, then viscosity and flow properties are improved, but thermal conductivity deteriorates

Engineering Contradiction:
Improveviscosity and flow propertiesVSAvoidthermal conductivity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The composition is segmented such that fine particles (5-20 μm) comprising 20-40% of the total provide excellent flow and low viscosity, while coarse particles (50-100 μm) comprising 20-40% provide the necessary thermal conductivity. The intermediate particles (20-50 μm) bridge these extremes, ensuring neither property dominates to the detriment of the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The ATH composition functions as a composite material system where particles of different sizes work synergistically. The fine particles act as lubricants improving flow, while coarse particles form thermal pathways, and intermediate particles connect these functions. This composite approach resolves the contradiction between viscosity improvement and thermal conductivity maintenance.

Inventive Principle:
Principle #40Composite materials

4Ease of operation

If a combination of ground and precipitated ATH particles is used, then viscosity properties are improved, but the composition complexity increases

Engineering Contradiction:
Improveviscosity propertiesVSAvoidcomposition complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The invention uses homogeneous ground ATH particles throughout the entire composition rather than mixing different production methods. All particles are ground to achieve the desired size distribution, eliminating the complexity of combining ground and precipitated ATH while still achieving excellent viscosity properties through the optimized particle size distribution.

Inventive Principle:
Principle #33Homogeneity

Data Source

PatentUS20240383766A1Aluminium trihydroxide compositions
Publication Date: 2024.11.21 SIBELCO DEUT GMBH
  • US20240383766A1 patent drawing
  • US20240383766A1 patent drawing
  • US20240383766A1 patent drawing

AI summary

The present invention relates to aluminium trihydroxide compositions. The present invention also relates to methods of forming aluminium trihydroxide compositions.