Atmosphere-Modulation Layer for Strain Retention in Semiconductor Annealing

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Solution Overview

Problem

The challenge in forming semiconductor devices is the limited thermal budget, which necessitates high-temperature thermal treatments for short durations, leading to poor performance and uniformity due to strain relaxation and thick equivalent oxide thickness (CET), especially for scaled-down dimensions and materials like Ge and III-V compounds.

Innovation Solution

The implementation of an atmosphere-modulation layer during high-pressure annealing with a low-thermal budget, controlling oxygen entry to improve interfacial layer uniformity and strain retention, allowing for longer annealing times without strain relaxation, and integrating gate dielectric and interfacial layer passivation in a single step.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high-temperature thermal treatment is performed, then reliability of the semiconductor device is improved, but the processing time must be shortened due to limited thermal budget, leading to poor device performance

Engineering Contradiction:
Improvereliability of the semiconductor deviceVSAvoidprocessing time
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies rapid thermal annealing (RTA) to change the thermal processing parameters, using high temperature for very short durations (seconds to minutes) instead of conventional slow annealing. This parameter change enables achieving the desired interface quality and device reliability while maintaining a limited thermal budget and short processing time.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs periodic or pulsed thermal treatment through RTA, where heating is applied in rapid pulses rather than continuous heating. This periodic thermal action allows the system to achieve the necessary thermal effects for interface passivation and material activation while keeping the overall thermal budget low and processing time short.

Inventive Principle:
Principle #19Periodic action

2Temperature

If high-temperature thermal treatment is performed for a short time, then thermal budget is maintained, but strain relaxation occurs and equivalent oxide thickness increases, leading to poor device performance

Engineering Contradiction:
Improvethermal budgetVSAvoidinterfacial layer uniformity and strain retention
Core Design Contradiction:
TemperatureVSManufacturing precision

Solution Approach 1:

The patent changes the thermal processing parameters by using rapid thermal annealing with controlled temperature profiles. By adjusting the heating rate, peak temperature, and duration, the process achieves interface passivation and material activation while maintaining strain in the semiconductor layer and preventing excessive oxide growth, thus preserving manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent performs preliminary formation of the interfacial layer before the rapid thermal annealing process. This preliminary action ensures that the interface is properly prepared, and subsequent RTA treatment enhances the interface quality without causing strain relaxation or excessive oxide thickening, as the interfacial layer is already in place to guide the thermal processing outcome.

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If conventional thermal treatment is used, then processing is simpler, but device performance and uniformity are poor due to strain relaxation and thick CET

Engineering Contradiction:
Improveprocessing simplicityVSAvoiddevice performance and uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent transforms the conventional slow thermal annealing process into rapid thermal annealing by changing the key parameter of heating rate. This parameter change maintains the relative simplicity of the manufacturing process (single-step annealing) while dramatically improving device performance and uniformity through better strain retention and controlled oxide thickness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the conventional gradual thermal diffusion mechanism with rapid thermal heating and cooling cycles. This substitution changes the fundamental mechanism of thermal processing from slow diffusion-based annealing to rapid thermal relaxation, achieving better interface quality and strain retention while maintaining process simplicity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the uniformity and reliability of semiconductor devices by maintaining low thermal budgets, reducing strain relaxation, and improving CET, while being suitable for high-mobility channel materials like Ge and III-V compounds.

Implementation Method 1

An annealing process is performed to form an interfacial layer between the channel and the atmosphere-modulation layer

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 2

controlling oxygen entry to improve interfacial layer uniformity

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS10879061B2Semiconductor device and method for forming the same
Publication Date: 2020.12.29 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US10879061B2 patent drawing
  • US10879061B2 patent drawing
  • US10879061B2 patent drawing

AI summary

Semiconductor devices and a method for forming the same are provided. In various embodiments, a method for forming a semiconductor device includes receiving a semiconductor substrate including a channel. An atmosphere-modulation layer is formed over the channel. An annealing process is performed to form an interfacial layer between the channel and the atmosphere-modulation layer.