Atmospheric CO2 Conversion to Methanol via Dehumidification

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Solution Overview

Problem

The increasing global warming due to fossil fuel combustion and the limited availability of fossil fuels necessitate the development of an alternative method to utilize carbon dioxide from the atmosphere for producing methanol and synthetic hydrocarbons, while also mitigating climate change.

Innovation Solution

A method involving the dehumidification of atmospheric air to separate water, followed by the absorption or adsorption of carbon dioxide, and subsequent conversion using hydrogenation to produce methanol, which can be further processed into dimethyl ether and synthetic hydrocarbons, utilizing energy sources like solar, wind, or geothermal energy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If carbon dioxide is captured and sequestered in subterranean cavities or under the sea, then carbon dioxide emissions are reduced, but the cost increases and there is a potential for leakage

Engineering Contradiction:
Improvecarbon dioxide emissionsVSAvoidsequestration safety
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent converts the harmful carbon dioxide into beneficial methanol fuel through catalytic conversion. Instead of merely storing CO2, the process transforms it into a useful energy carrier that can replace fossil fuels, thereby addressing both climate change and energy security simultaneously

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent changes the chemical state of carbon dioxide from a greenhouse gas to a valuable chemical feedstock by altering its molecular structure through hydrogenation and catalysis, transforming it from waste to resource

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If carbon dioxide is captured and sequestered, then carbon dioxide emissions are reduced, but the cost increases

Engineering Contradiction:
Improvecarbon dioxide emissionsVSAvoidsequestration cost
Core Design Contradiction:
Object-affected harmful factorsVSUse of energy by moving object

Solution Approach 1:

The patent transforms the waste carbon dioxide into valuable methanol fuel, creating a revenue stream that can offset the costs of CO2 capture and processing. This converts a costly waste management problem into a profitable chemical production process

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The process uses carbon dioxide from industrial exhaust streams as a feedstock for methanol production, making the system self-sufficient by utilizing available waste resources rather than requiring additional raw material inputs

Inventive Principle:
Principle #25Self-service

3Power

If fossil fuels are used to generate energy, then energy demand is met, but carbon dioxide emissions increase

Engineering Contradiction:
Improveenergy generationVSAvoidcarbon dioxide emissions
Core Design Contradiction:
PowerVSObject-generated harmful factors

Solution Approach 1:

The patent recovers carbon dioxide that would otherwise be discarded into the atmosphere from industrial processes and converts it into methanol fuel, thereby recovering a valuable resource while preventing greenhouse gas emissions

Inventive Principle:
Principle #34Discarding and recovering

Solution Approach 2:

The patent fundamentally changes the role of carbon dioxide from a harmful emission to a valuable feedstock by altering its chemical parameters through catalytic hydrogenation, enabling it to serve as a building block for fuel production

Inventive Principle:
Principle #35Parameter changes

4Quantity of substance

If atmospheric carbon dioxide is used as raw material, then an inexhaustible carbon source is provided, but the complexity of separation and purification increases

Engineering Contradiction:
Improvecarbon source availabilityVSAvoidseparation and purification process
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent extracts carbon dioxide from atmospheric air through selective absorption or adsorption processes, isolating the required component from the complex air mixture for subsequent conversion to methanol

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs intermediary substances such as absorbents or adsorbents that facilitate the separation of carbon dioxide from air, simplifying the overall process by using a mediating material to perform the separation function

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method provides an inexhaustible source of methanol and synthetic hydrocarbons, reducing carbon dioxide emissions and offering a sustainable alternative to fossil fuels, while being economically viable and universally applicable.

Implementation Method 1

removing water from atmospheric air by dehumidification of moisture therefrom

Methodology Applied
Scientific EffectDehumidification: Condensation

Implementation Method 2

obtaining carbon dioxide by absorption or adsorption from the dehumidified atmospheric air

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

obtaining carbon dioxide by absorption or adsorption from the dehumidified atmospheric air

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

converting the carbon dioxide thus obtained by suitable methods of reduction and hydrogenation under conditions sufficient to produce methanol

Methodology Applied
Scientific EffectHydrogenation: Hydrogenation

Data Source

PatentUS7459590B2Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material
Publication Date: 2008.12.02 UNIV OF SOUTHERN CALIFORNIA

AI summary

A method for producing methanol and dimethyl ether using the air as the sole source of materials is disclosed. The invention relates to a method for producing methanol by removing water from atmospheric air, obtaining hydrogen from the removed water, obtaining carbon dioxide from atmospheric air; and converting the carbon dioxide under conditions sufficient to produce methanol. Thereafter, the methanol can be dehydrated to produce dimethyl ether or further processed to produce synthetic hydrocarbons, polymers, and products derived from them.