Atomic-Layer Semiconductor Etching for Precision and Throughput

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Solution Overview

Problem

Current etching methods for semiconductor processing face challenges in achieving high precision and selectivity, particularly in forming nanowires or nanosheets, due to varying selectivity ratios of different materials, which are difficult to satisfy the increasing demands of smart electronic devices.

Innovation Solution

The method involves forming a modified layer of one or several atom layers on a semiconductor material surface using a modifier, followed by controlled removal of this layer, with optional cleaning steps using specific agents, to achieve precise control over etching thickness and improve etching rate, allowing for isotropic reactions and self-limited processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional etching methods are used to achieve high etching precision, then the etching precision requirement can be met, but the processing efficiency and productivity are significantly reduced

Engineering Contradiction:
Improveetching precisionVSAvoidprocessing efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The etching process is divided into multiple cycles, where each cycle includes forming a modified layer and removing it. This segmentation allows precise control of etching thickness in each cycle while maintaining high productivity through repeated efficient cycles.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The etching process employs periodic action through cyclic repetition of modified layer formation and removal. Each cycle etches a controlled thickness, and multiple cycles achieve the total required etching depth with high precision and efficiency.

Inventive Principle:
Principle #19Periodic action

2Adaptability or versatility

If different selectivity ratios are used for etching different materials, then material selectivity is improved, but the complexity of process control increases due to substantial differences between selectivity ratios

Engineering Contradiction:
Improvematerial selectivityVSAvoidprocess control complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

A modified layer is introduced as an intermediary between the etching agent and the semiconductor material. This modified layer has different etching rates for different materials, providing material selectivity while simplifying process control since the modified layer formation and removal can be uniformly controlled.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If the etching process is made more selective to preserve remaining semiconductor material, then the integrity of unetched regions is improved, but the etching rate and productivity are reduced

Engineering Contradiction:
Improveintegrity of remaining materialVSAvoidetching rate
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

A modified layer is formed preliminarily on the semiconductor material surface before the actual etching step. This modified layer serves as a protective barrier that preserves the integrity of the material during etching while allowing controlled removal to achieve the desired etching rate and productivity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables precise control of etching thickness to 0.5 nm or less, improving etching precision and rate, while preventing further reactions and ensuring processing quality by cyclically forming and removing the modified layer.

Implementation Method 1

forming a modified layer having a thickness of one or several atom layers on a selected region of a surface of a semiconductor material layer by using a modifier

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

the reaction is self-limited

Methodology Applied
Scientific EffectSelf-limited reaction:

Data Source

PatentUS11827988B2High-precision etching method
Publication Date: 2023.11.28 INST OF MICROELECTRONICS CHINESE ACAD OF SCI LTD
  • US11827988B2 patent drawing
  • US11827988B2 patent drawing
  • US11827988B2 patent drawing

AI summary

An embodiment of the present disclosure provides an etching method, having the following steps: forming a modified layer having a thickness of one or several atom layers on a selected region of a surface of a semiconductor material layer by using a modifier; and removing the modified layer. When a semiconductor is processed, this method achieves precise control over the etching thickness and improves the etching rate at the same time.