Au-Sn Alloy Bump Void Control via Sn-Rich Crystal Phase

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Solution Overview

Problem

Au—Sn alloy bumps produced using a paste with 20 mass % Sn and the balance Au and unavoidable impurities often contain large voids, which lead to unreliable jointing due to cracking, necessitating the development of bumps without voids larger than 30% of the bump diameter.

Innovation Solution

The production of Au—Sn alloy bumps involves mixing Au—Sn alloy powder with flux and subjecting it to reflow treatment, where the powder composition contains Sn: 20.5 to 23.5 mass % and a structure with 0.5 to 30 area % Sn-rich primary crystal phase, ensuring no large voids by controlling the mixing and atomization process to prevent Au-rich primary crystal phase growth and enhance flowability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional Au—Sn alloy powder with 20 mass % Sn composition is used for producing Au—Sn alloy bumps, then the bumps can be formed through reflow treatment, but large residual voids are generated in the interior of the bumps

Engineering Contradiction:
Improvejointing reliabilityVSAvoidvoid size control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention changes the compositional parameters by specifying Sn content of 20.5 to 23.5 mass % (narrowing the range around the conventional 20 mass %) and controls the microstructural parameters by limiting Sn-rich primary crystal phase to 0.5 to 30 area %. These parameter changes optimize the melting behavior and crystal growth during reflow, preventing large void formation while maintaining jointing reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies local quality control by specifying the distribution and amount of Sn-rich primary crystal phase within the alloy powder structure. By controlling that 0.5 to 30 area % of Sn-rich primary crystal phase is crystallized in the matrix, the local microstructure is optimized to control void formation during reflow, addressing the void issue without compromising overall bump integrity

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If Au—Sn alloy powder is obtained by gas-atomizing process with 20 mass % Sn composition, then the powder can be used for solder paste, but large residual voids remain in the produced bumps

Engineering Contradiction:
Improvepowder productionVSAvoidjointing reliability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention modifies the compositional parameters by adjusting Sn content to 20.5 to 23.5 mass % and controls the microstructural parameters by limiting Sn-rich primary crystal phase to 0.5 to 30 area %. These parameter changes optimize the melting behavior and crystal growth during reflow, preventing large void formation while maintaining jointing reliability

Inventive Principle:
Principle #35Parameter changes

3Productivity

If reflow treatment is applied to Au—Sn alloy paste to form bumps, then the bumps can be created on substrate surface, but large voids are trapped in the interior

Engineering Contradiction:
Improvebump formation efficiencyVSAvoidvoid elimination
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The invention applies preliminary action by pre-controlling the microstructure of the Au—Sn alloy powder before the reflow process. By ensuring that 0.5 to 30 area % of Sn-rich primary crystal phase is crystallized in the matrix before reflow, the alloy is prepared in advance to melt and flow properly, enabling void-free bump formation during the subsequent reflow treatment

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention optimizes the compositional parameters (Sn: 20.5 to 23.5 mass %) and microstructural parameters (Sn-rich primary crystal phase: 0.5 to 30 area %) to control the melting and solidification behavior during reflow, enabling efficient bump formation without trapped voids

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method results in Au—Sn alloy bumps with reduced voids, enhancing the reliability of semiconductor device joints and reducing defective product rates, thereby lowering production costs.

Implementation Method 1

subjecting the Au—Sn alloy paste to reflow melting and forming Au—Sn alloy bumps on the surface of the substrate

Methodology Applied
Scientific EffectReflow melting: Melting

Implementation Method 2

a structure containing 0.5 to 30 area % of Sn-rich primary crystal phase crystallized in the matrix

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS8721961B2Au—Sn alloy bump including no large void and method of producing same
Publication Date: 2014.05.13 MITSUBISHI MATERIALS CORP
  • US8721961B2 patent drawing
  • US8721961B2 patent drawing
  • US8721961B2 patent drawing

AI summary

An Au—Sn alloy bump that does not include large voids and a method of producing the same are provided. The Au—Sn alloy bump that does not include large voids comprises a composition containing Sn: 20.5 to 23.5 mass % and the balance Au and unavoidable impurities, and a structure where 0.5 to 30 area % of Sn-rich primary crystal phase is crystallized in the matrix.