Austenitic Stainless Steel Gasket Composition for Fatigue Resistance

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Solution Overview

Problem

Metastable austenitic stainless steel metal gaskets face issues with anisotropy in workability and fatigue resistance due to coarse oxide inclusions, leading to performance deterioration under severe conditions, and martensitic stainless steel lacks work hardening, resulting in inadequate high-temperature softening resistance and potential hot rolling cracking.

Innovation Solution

A hot rolled austenitic stainless steel sheet with a specific chemical composition and optimized oxide inclusion composition, featuring increased Mn content and controlled δ ferrite phase formation, reduces anisotropy and enhances high-temperature softening resistance, preventing hot rolling cracking and maintaining uniform contact pressure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the cold rolling reduction ratio is increased to enhance strength in metastable austenitic stainless steel, then strength is improved, but toughness, fatigue resistance characteristics, and workability deteriorate

Engineering Contradiction:
ImprovestrengthVSAvoidfatigue resistance characteristics
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the material composition parameters by adding specific amounts of Ti (0.01-0.50%), Nb (0.01-0.50%), B (0.0005-0.020%), and controlling Al content (0.003-0.030%), along with specific ranges of C, Si, Mn, Ni, Cr, Cu, and N. These compositional parameter changes enable achieving high strength without excessive cold rolling reduction, thereby maintaining fatigue resistance and workability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of austenite matrix with deformation-induced martensite and controlled oxide inclusions. This composite structure provides both high strength through martensite formation and maintained fatigue resistance through the austenite matrix and controlled inclusion characteristics.

Inventive Principle:
Principle #40Composite materials

2Strength

If the cold rolling reduction ratio is increased to enhance strength, then strength is improved, but bending workability and toughness deteriorate

Engineering Contradiction:
ImprovestrengthVSAvoidbending workability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent modifies material parameters by controlling chemical composition (adding Ti, Nb, B, and controlling Al) and microstructure (austenite with deformation-induced martensite). These changes enable achieving high strength with reduced cold rolling reduction ratio, thereby preserving bending workability and toughness.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If coarse oxide based inclusions are present in successive form in rolling direction, then material simplicity is maintained, but anisotropy in workability and fatigue resistance occurs

Engineering Contradiction:
Improvematerial simplicityVSAvoidfatigue resistance characteristics
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent changes the inclusion characteristics by controlling their size (10 μm or less), shape (extended in rolling direction), and composition (specific Al2O3-SiO2-MnO system with controlled ratios). These parameter changes eliminate anisotropy in fatigue resistance while maintaining material simplicity and processing ease.

Inventive Principle:
Principle #35Parameter changes

4Temperature

If Mn content is increased to enhance high temperature softening resistance, then high temperature performance is improved, but risk of hot rolling cracking increases

Engineering Contradiction:
Improvehigh temperature softening resistanceVSAvoidhot rolling cracking
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The patent optimizes Mn content within specific ranges (1.50-3.00% for first embodiment, 0.90-17.00% for second embodiment) and balances it with other alloying elements (Ti, Nb, B, Al, C, Si, Ni, Cr, Cu, N). This balanced compositional approach achieves high temperature softening resistance while preventing hot rolling cracking through controlled δ ferrite phase formation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a multi-element alloy system where Mn works synergistically with Ti, Nb, B, and other elements to achieve both high temperature resistance and crack prevention. The composite microstructure of austenite with controlled δ ferrite and deformation-induced martensite provides both required properties.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly improves workability and fatigue resistance characteristics, ensuring high-dimensional accuracy and leakage resistance, while providing excellent high-temperature performance and durability for metal gaskets.

Implementation Method 1

the reduction of the "anisotropy" can be achieved by softening the oxide based inclusion present in the steel sheet

Methodology Applied
Scientific EffectSoftening of oxide based inclusion:

Implementation Method 2

The steel of this type achieves a high strength through formation of deformation induced martensite by cold rolling

Methodology Applied
Scientific EffectDeformation induced martensite formation: Phase Change

Implementation Method 3

the dislocation anchoring effect of the interstitial solid solution elements (C and N) bearing the strain aging is difficult to release

Methodology Applied
Scientific EffectDislocation anchoring effect:

Implementation Method 4

for preventing the "hot rolling cracking", it is effective to optimize the formation amount of the δ ferrite phase

Methodology Applied
Scientific Effectδ ferrite phase formation: Phase Change

Data Source

PatentUS10060003B2Austenitic stainless steel sheet and metal gasket
Publication Date: 2018.08.28 NIPPON STEEL STAINLESS STEEL CORP
  • US10060003B2 patent drawing
  • US10060003B2 patent drawing

AI summary

A hot rolled austenitic stainless steel sheet contains 0.030 to 0.300% of C, from 0.30 to 3.20% of Si, from 0.90 to 17.00% of Mn, from 1.00 to 8.00% of Ni, from 14.00 to 19.00% of Cr, from 0.50 to 3.50% of Cu, from 0.045 to 0.250% of N, from 0.0001 to 0.0300% of Al, from 0 to 0.50% of V, from 0 to 0.50% of Nb, from 0 to 0.30% of Ti, and from 0 to 0.010% of B, all in terms of percentage by mass, with the balance of Fe and unavoidable impurities, has a converted average composition of an oxide based inclusion that contains 30% by mass or less of Al2O3, 60% by mass or less of SiO2, and 15% by mass or more of MnO, and satisfies MnO3—3SiO2+110. Anisotropy of workability and fatigue resistance characteristics caused by an oxide based inclusion is decreased.