Organic Azacyclophane Compounds for OLED Charge Transport

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Solution Overview

Problem

There is a need for novel hosts and charge transporting/blocking materials that can improve the performance of organic light-emitting diodes (OLEDs).

Innovation Solution

A compound with the structure of Formula I is provided, which can be used in OLEDs as a host or charge transporting/blocking material, comprising a specific arrangement of carbon and nitrogen atoms with various substituents, enhancing the device's performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional host materials are used in OLEDs, then the device structure is simple and easy to manufacture, but the charge transport and blocking performance is insufficient leading to lower efficiency and shorter longevity

Engineering Contradiction:
ImproveOLED efficiency and longevityVSAvoidcompound structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure parameters of host materials by incorporating specific heterocyclic rings (triazine, pyrimidine, pyridine) with nitrogen atoms at defined positions (X1-X8), and by systematically varying substituent groups (G1-G6, R1-R6) to optimize charge transport and blocking properties, thereby improving OLED efficiency and longevity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite molecular structures by combining multiple heterocyclic rings (such as dibenzofuran, dibenzothiophene, carbazole) with functional substituents to form complex host materials that exhibit superior charge transport and blocking characteristics compared to conventional single-structure materials

Inventive Principle:
Principle #40Composite materials

2Productivity

If existing charge transporting/blocking materials are used, then the manufacturing process is straightforward, but the charge transport and blocking capabilities are limited

Engineering Contradiction:
Improvecharge transport and blocking efficiencyVSAvoidsynthesis complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent divides the host material molecule into distinct functional segments: core heterocyclic rings (providing structural framework), nitrogen atoms at specific positions (providing charge transport pathways), and variable substituent groups (G1-G6, R1-R6) that can be independently optimized for specific charge blocking or transport functions, allowing systematic improvement of efficiency

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent designs a universal host material platform based on Formula I that can serve multiple functions simultaneously: charge transport, charge blocking, and exciton management, by appropriately selecting the heterocyclic core and substituent groups, thereby improving overall device efficiency without requiring multiple separate materials

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound improves OLED performance by optimizing the transport and blocking of charges, leading to enhanced efficiency and longevity of the organic light-emitting devices.

Implementation Method 1

OLEDs make use of thin organic films that emit light when voltage is applied across the device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10964893B2Organic electroluminescent materials and devices
Publication Date: 2021.03.30 UNIVERSAL DISPLAY CORP
  • US10964893B2 patent drawing
  • US10964893B2 patent drawing
  • US10964893B2 patent drawing

AI summary

The present invention discloses organic azacyclophane compounds with two substituted triazine, pyridine, pyrimidine or pyrazine rings. These materials may serve as hosts, charge transporting and blocking materials and may improve OLED performance.