Azeotropic like composition containing 2-chloro-1,3,3,3-tetrafluoropropene and 1-chloro-3,3,3-trifluoropropene

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Solution Overview

Problem

Current azeotropic compositions and azeotropic-like compositions for refrigeration and cleaning applications face challenges in maintaining a consistent composition ratio between the liquid and gas phases, leading to inefficiencies and environmental concerns due to volatility and flammability.

Innovation Solution

A specific azeotropic-like composition comprising 2-chloro-1,3,3,3-tetrafluoropropene (HCFO-1224xe) and 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) is developed, which maintains a stable composition ratio in both phases, reducing environmental impact and flammability, and is suitable for use as a washing detergent, solvent, foaming agent, coolant, and heat transfer medium.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If conventional azeotropic compositions are used, then refrigeration and cleaning performance is achieved, but composition ratio consistency between liquid and gas phases deteriorates due to volatility

Engineering Contradiction:
Improvecomposition ratio consistencyVSAvoidvolatility
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by using specific HFO compounds (1-chloro-3,3,3-trifluoropropene and 2-chloro-1,3,3,3-tetrafluoropropene) with controlled ratios to form an azeotropic mixture that maintains consistent composition between phases, thereby reducing volatility-related composition changes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite azeotropic mixture combining two different HFO compounds in specific proportions, where the synergistic interaction between components achieves both refrigeration performance and composition stability that neither component could achieve alone

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional azeotropic compositions are used, then cleaning performance is achieved, but flammability increases

Engineering Contradiction:
Improvecleaning performanceVSAvoidflammability
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the chemical composition by selecting specific HFO compounds and their ratios to achieve optimal balance between cleaning performance and flammability reduction, utilizing the unique properties of each component

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potential harm of flammability into a benefit by carefully selecting component ratios that reduce flammability while maintaining or enhancing cleaning performance, effectively transforming a harmful property into a controlled and beneficial characteristic

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition ensures stable performance and reduced environmental impact by maintaining a consistent composition ratio, enhancing washing capabilities and heat transfer characteristics while being non-flammable and having minimal environmental influence.

Implementation Method 1

it is preferable that the mixture is an azeotropic or azeotropic-like composition, which is volatilized with substantially the same composition ratio as that of a liquid phase

Methodology Applied
Scientific EffectAzeotropic behavior:

Data Source

PatentEP3202882B1Azeotropic like composition containing 2-chloro-1,3,3,3-tetrafluoropropene and 1-chloro-3,3,3-trifluoropropene
Publication Date: 2019.09.18 CENT GLASS CO LTD
  • EP3202882B1 patent drawingFigure 1
  • EP3202882B1 patent drawingFigure 2
  • EP3202882B1 patent drawingFigure 3

AI summary

Provided is an azeotropic like composition that contains 2-chloro-1,3,3,3-tetrafluoropropene and 1-chloro-3,3,3-trifluoropropene. According to the azeotropic like composition of the present invention, a composition, which is nonflammable and environment-friendly and in which the liquid phase composition and gas phase composition are substantially the same, can be provided. Moreover, use of the azeotropic mixture-like composition according to the present invention makes it possible to provide a detergent, a solvent, a silicone solvent, a foaming agent, a coolant or heat medium for a heat pump, or a high-temperature working fluid, each being nonflammable and environment-friendly and the liquid phase composition and gas phase composition therein being substantially the same.