Aziridine Primer for Proteinaceous Substrate Adhesion

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Solution Overview

Problem

Current methods for improving adhesion between nail polishes and prosthetic materials and proteinaceous substrates, such as fingernails and hooves, are often toxic, cause harm due to physical abrasion, and result in poor bond strength, leading to premature failure of the polish or prosthesis.

Innovation Solution

A solution comprising a polyfunctional aziridine component in a non-reactive solvent, such as propylene glycol mono-methyl ether, is applied to the substrate to create a primed surface, enhancing adhesion without the use of harsh chemicals, thereby improving the bond strength and safety.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If physical abrasion and roughening of the proteinaceous substrate surface is used to improve adhesion, then adhesion is improved, but the substrate and surrounding cuticles are harmed

Engineering Contradiction:
ImproveadhesionVSAvoidsubstrate damage
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

A primer composition acts as an intermediary between the proteinaceous substrate and the coating or prosthesis. The primer contains functional groups that bond to the substrate and provide anchoring points for the topcoat, eliminating the need for harsh physical abrasion while achieving strong adhesion through chemical bonding mechanisms.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If unsaturated carboxylic acid solutions are applied to improve adhesion, then adhesion is improved, but the protein of the substrate and surrounding living tissue is severely damaged

Engineering Contradiction:
ImproveadhesionVSAvoidtissue damage
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The primer uses alternative chemical parameters - specifically functional groups with appropriate pKa values and bonding characteristics - instead of highly corrosive unsaturated carboxylic acids. This changes the chemical nature of the adhesion promoter to be less damaging while maintaining effective bonding capability to the proteinaceous substrate.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If lower concentrations of unsaturated acids are used to reduce toxicity, then safety is improved, but adhesion is minimized or lost completely

Engineering Contradiction:
ImprovetoxicityVSAvoidadhesion
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The primer composition is a composite formulation containing multiple functional components including buffering agents, functional groups with specific bonding characteristics, and optional adhesion promoters. This composite approach achieves effective adhesion at safe, lower concentrations by combining multiple mild functional elements rather than relying on high concentrations of a single corrosive acid.

Inventive Principle:
Principle #40Composite materials

4Strength

If harsh surface preparation is applied to improve adhesion, then adhesion is improved, but the bond strength is still poor and inadequate to retain the polish or prosthesis

Engineering Contradiction:
ImproveadhesionVSAvoidbond durability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The primer is applied as a preliminary step before the topcoat or prosthesis, creating a prepared surface with optimal bonding characteristics. This preliminary action of applying the primer allows subsequent layers to bond effectively, achieving both strong initial adhesion and long-term bond durability without requiring harsh surface preparation.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method provides a non-toxic, odorless, and significant improvement in adhesive bond strength between coatings or composites and proteinaceous substrates, outperforming existing methods by maintaining polish integrity and prosthesis adherence over time.

Implementation Method 1

a polyfunctional aziridine component in a non-reactive solvent capable of solubilizing the polyfunctional aziridine component

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 2

The reparation, adornment, and prosthetic extension of proteinaceous structures... has been a common practice for centuries

Methodology Applied
Scientific EffectRing-opening reaction: Chemical Bonding

Data Source

PatentUS9636287B2Primecoat compositions for proteinaceous substrates and methods of priming proteinaceous substrates therewith
Publication Date: 2017.05.02 MAD RIVER SCI
  • US9636287B2 patent drawing
  • US9636287B2 patent drawing
  • US9636287B2 patent drawing

AI summary

Compositions containing a solution of a polyfunctional aziridine component in a non-reactive solvent, and methods of applying such compositions to proteinaceous substrates, such as fingernails and toenails, to provide primed substrates which may be further coated.