Backside Wafer Metallization Using MOD Inkjet Printing

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Solution Overview

Problem

Conventional semiconductor wafer metallization methods face challenges such as high equipment costs, low material utilization, and inadequate adhesion and electrical conductivity, particularly for large wafers and thick metallization layers.

Innovation Solution

The method involves applying a Metal-Organic Decomposition (MOD) ink composition to the semiconductor wafer, followed by curing, using inkjet printing for efficient and cost-effective deposition, which allows for the formation of dense, thick metallization layers with improved adhesion and conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional sputtering/evaporation methods are used for metallization, then the metallization layer can be formed, but the equipment cost is high and material utilization is low

Engineering Contradiction:
Improvemetallization qualityVSAvoidequipment cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces the mechanical vacuum-based sputtering/evaporation system with a chemical solution-based printing system. The MOD ink composition is applied through printing techniques, eliminating the need for expensive vacuum chambers and sputtering equipment while achieving comparable metallization quality through chemical decomposition and metal deposition.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses disposable printing materials and solutions instead of expensive, maintainable vacuum equipment. The MOD ink composition can be applied using standard printing technology, reducing equipment investment and operational costs while maintaining metallization effectiveness.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If conventional sputtering/evaporation methods are used for metallization, then the metallization layer can be formed, but material utilization is low

Engineering Contradiction:
Improvemetallization qualityVSAvoidmaterial utilization
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent replaces the mechanical vacuum-based sputtering/evaporation system with a chemical solution-based printing system. The MOD ink composition is applied through printing techniques, eliminating the need for expensive vacuum chambers and sputtering equipment while achieving comparable metallization quality through chemical decomposition and metal deposition.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent improves material utilization by applying metal precursors only where needed through patterned printing, rather than coating the entire wafer surface. Excess material can be recovered or the process uses minimal excess, significantly improving material efficiency compared to conventional methods.

Inventive Principle:
Principle #34Discarding and recovering

3Strength

If the metallization layer is made thicker to improve adhesion, then adhesion improves, but the wafer warpage increases due to stress

Engineering Contradiction:
ImproveadhesionVSAvoidwafer warpage
Core Design Contradiction:
StrengthVSShape

Solution Approach 1:

The patent changes the chemical composition and stress characteristics of the metallization layer by using MOD ink with specific metal precursors and organic vehicles. This allows achieving adequate adhesion with thinner layers or different layer compositions that have reduced stress, thereby minimizing wafer warpage while maintaining adhesion requirements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite metallization structures with multiple layers having different stress characteristics. By combining layers with complementary properties, the overall structure achieves good adhesion while the stress is distributed and balanced, reducing net warpage on the wafer.

Inventive Principle:
Principle #40Composite materials

4Ease of manufacture

If printing techniques are used for metallization, then equipment cost is reduced, but the adhesion and electrical conductivity need further improvement

Engineering Contradiction:
Improveequipment costVSAvoidadhesion and conductivity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent optimizes the chemical composition, drying conditions, and firing parameters of the MOD ink to enhance both adhesion and electrical conductivity. By controlling the decomposition temperature, metal precursor concentration, and organic vehicle composition, the process achieves reliable metallization properties comparable to conventional methods while using cost-effective printing equipment.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in metallization layers with enhanced adhesion and electrical conductivity, comparable to PVD methods, while reducing equipment costs and material waste, and is suitable for large wafers, overcoming the limitations of prior art.

Implementation Method 1

curing the precursor layer

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 2

applying a Metal-Organic Decomposition (MOD) ink composition to the semiconductor wafer, thereby forming a precursor layer

Methodology Applied
Scientific EffectInkjet deposition:

Data Source

PatentUS20240030039A1Metallization of semiconductor wafer
Publication Date: 2024.01.25 HERAEUS ELECTRONICS GMBH & CO KG
  • US20240030039A1 patent drawing

AI summary

The present invention relates to a method for manufacturing a semiconductor wafer comprising: i) applying a MOD ink composition to a semiconductor wafer, thereby forming a precursor layer; and ii) curing the precursor layer. In an embodiment, the application in step i) is carried out by inkjet printing. The method for inkjet printing MOD ink has low equipment cost and low power consumption; no material waste; on-demand printing and easy selective deposition/design flexibility (no etching required). In addition, the method of the present invention improves the adhesion and electric conductivity of the metallization layer on backside of the wafer.