Ballasted Flocculation Adsorbent Recycling

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Solution Overview

Problem

The existing water treatment techniques, particularly those involving adsorption, face challenges due to poor control of adsorbent reagent consumption, leading to either insufficient or excessive reagent use, resulting in subpar water quality and increased costs.

Innovation Solution

A process that includes a pre-contact zone with powdered adsorbent, followed by ballasted flocculation and settling, with continuous measurement and controlled injection of new adsorbent reagent to maintain optimal concentration, and acidification to enhance adsorption capacity, recycling sludge and adsorbent to reduce waste and consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If adsorbent reagent is injected into water treatment zones, then the content of dissolved and suspended impurities is reduced, but the consumption of adsorbent reagent becomes uncontrolled leading to either insufficient treatment or excessive reagent presence in treated water

Engineering Contradiction:
Improvewater qualityVSAvoidadsorbent reagent consumption
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The adsorbent reagent is pre-mixed with sludge from the settling zone to form a pre-treated adsorbent mixture before being reintroduced to the coagulation-flocculation process. This preliminary preparation optimizes the adsorbent's effectiveness and controls its consumption by ensuring it is properly conditioned before contact with raw water.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Instead of discarding the sludge from the settling zone, it is recovered and reused as a carrier for the adsorbent reagent. This recycling approach controls reagent consumption by concentrating the adsorbent on the sludge particles, which are then removed with the flocs, preventing excessive adsorbent presence in the treated water.

Inventive Principle:
Principle #34Discarding and recovering

2Manufacturing precision

If excessive adsorbent reagent is supplied to reduce impurities, then the reduction of colloidal impurities is significant, but the treated water quality deteriorates due to high presence of particles in the water

Engineering Contradiction:
Improveimpurity reductionVSAvoidtreated water quality
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The sludge containing the adsorbent reagent and adsorbed impurities is recovered from the settling zone and reused in the coagulation-flocculation process. This ensures that the adsorbent, along with the captured impurities, is removed with the flocs, preventing particle overload in the treated water while maintaining effective impurity reduction.

Inventive Principle:
Principle #34Discarding and recovering

Solution Approach 2:

The system creates a feedback loop where the sludge from the settling zone is returned to the coagulation-flocculation zone, allowing the adsorbent to work in a controlled cycle. This feedback mechanism ensures optimal adsorbent utilization and prevents excessive reagent accumulation in the treated water.

Inventive Principle:
Principle #23Feedback

3Quantity of substance

If insufficient adsorbent reagent is supplied, then the treatment cost is reduced, but the reduction by adsorption of impurities is limited and treated water does not meet drinkability criteria

Engineering Contradiction:
Improveadsorbent reagent consumptionVSAvoidwater quality
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The sludge is recovered and reused as a carrier for the adsorbent reagent, which concentrates the adsorbent on solid particles. This increases the effective adsorption capacity per unit of adsorbent reagent, allowing for reduced overall consumption while maintaining or improving treatment effectiveness.

Inventive Principle:
Principle #34Discarding and recovering

Solution Approach 2:

The system creates a composite material by combining sludge and adsorbent reagent together. This composite structure enhances the adsorption efficiency, allowing the adsorbent to work more effectively on the sludge particles, thereby improving impurity removal while controlling reagent consumption.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach ensures the production of high-quality water while minimizing adsorbent consumption and treatment costs, maintaining effective adsorption capacity and reducing residual adsorbent in treated water.

Implementation Method 1

The treatment of water by adsorption is most often obtained by injecting into the water at least one reagent having adsorbent properties such as activated carbon

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

The injection of ballast leads to the relatively rapid formation of ballasted floc whose settling speed is increased compared to that of a conventional floc

Methodology Applied
Scientific EffectSettling: Settling

Implementation Method 3

Coagulation generates an agglomeration of colloidal particles suspended in water

Methodology Applied
Scientific EffectCoagulation: Coagulation

Implementation Method 4

Flocculation causes the formation of flocs by agglomeration of previously coagulated colloidal particles

Methodology Applied
Scientific EffectFlocculation: Flocculation

Data Source

PatentEP2382163B1Method for treating water by ballasted flocculation and settlement, including pre-contacting the water with an adsorbent
Publication Date: 2013.05.29 VEOLIA WATER SOLUTIONS & TECHNOLOGIES SUPPORT SAS
  • EP2382163B1 patent drawingFigure 1

AI summary

The invention relates to a method for treating raw water laden with impurities in a treatment facility including at least one step of placing water in contact with a powdered adsorbent agent in an agitated pre-contact area (2), a step of ballasted flocculation, a step of settling, extracting a mixture of sludge, ballast and the powdered adsorbent agent from the bottom of the settlement area (5), and inserting the mixture in a hydrocyclone (11), transporting the overflow consisting of a mixture of sludge and powdered adsorbent reagent from said hydrocyclone (11) to a transition area (14). The method also includes a step of recycling the mixture of sludge and powdered adsorbent agent from the transition area (14) in the pre-contact area (2), continuously measuring at least one datum showing the concentration of powdered adsorbent agent in the pre-contact area (2), and a step of injecting a suspension of new powdered adsorbent agent in an aqueous medium upstream when the concentration of powdered adsorbent agent in the pre-contact area (2) is below a predetermined threshold value, as well as a step of acidifying said suspension of adsorbent agent.