Composite Barrel Spring Coating for Watch Friction Reduction

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Solution Overview

Problem

Conventional coatings for barrel springs in mechanical watches fail to maintain cohesion and reduce friction effectively due to deformation stresses, leading to breakage or delamination during winding and uncocking.

Innovation Solution

A barrel spring made of a polymer matrix with fibers, coated with a slow-curing epoxy resin having a gelling time greater than 20 minutes at 90°C, which is homogenized and polymerized to form a coating that reduces friction and maintains cohesion through hydrogen or Van der Waals bonds.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a conventional coating (metallic or DLC) is applied to the barrel spring, then friction between turns is reduced, but the coating breaks or delaminates under deformation stress

Engineering Contradiction:
Improvefriction between turnsVSAvoidcoating cohesion
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical composition and bonding characteristics of the coating material from conventional metallic or DLC coatings to an organic coating containing silicon-oxygen-silicon bonds and hydrogen bonds. This parameter change in material composition allows the coating to maintain flexibility and adhesion under deformation while still providing friction reduction.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The coating is formulated as a composite material containing silicon oxide (SiOx) with specific silicon-oxygen-silicon bond angles (140°-180°) and hydrogen bonds. This composite structure combines the hardness and lubricity of silicon oxide with the flexibility and adhesion of hydrogen bonding, resolving the contradiction between friction reduction and coating cohesion.

Inventive Principle:
Principle #40Composite materials

2Strength

If a ceramic or diamond coating with covalent/ionic bonds is used, then coating hardness is improved, but the coating cannot ensure satisfactory cohesion under deformation

Engineering Contradiction:
Improvecoating hardnessVSAvoidcoating cohesion
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the bonding mechanism from rigid covalent/ionic bonds to a combination of silicon-oxygen-silicon bonds with specific geometry (140°-180° angles) and hydrogen bonds. This parameter change provides a balance between hardness (from SiOx structure) and flexibility/cohesion (from hydrogen bonding and bond angle flexibility).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The silicon-oxygen-silicon bond structure acts as an intermediary between the rigid SiOx network and the flexible hydrogen bonding. The specific bond angles (140°-180°) allow the coating to accommodate deformation while maintaining structural integrity and cohesion.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces friction between turns and ensures the coating's cohesion, even under significant deformations, thereby enhancing the power reserve and longevity of mechanical watches without increasing the watch's bulk.

Implementation Method 1

The coating reduces friction on the spring turns

Methodology Applied
Scientific EffectFriction reduction: Friction

Implementation Method 2

a coating whose elastic behavior is ensured by covalent or ionic type bonds, such as a ceramic or diamond coating

Methodology Applied
Scientific EffectHydrogen bonding: Hydrogenation

Implementation Method 3

The coating has good cohesion... through hydrogen or Van der Waals bonds

Methodology Applied
Scientific EffectVan der Waals force: Van der Waals Force

Implementation Method 4

a barrel spring made of a material comprising a polymer matrix containing fibers

Methodology Applied
Scientific EffectComposite material reinforcement: Composite Materials

Data Source

PatentEP2788821B1Sliding layer for a barrel spring made of a composite material
Publication Date: 2019.04.10 CARTIER INTERNATIONAL AG
  • EP2788821B1 patent drawingFigure 1~3
  • EP2788821B1 patent drawingFigure 2

AI summary

Mainspring for driving a clock movement, said mainspring being made of a material comprising a polymer matrix containing fibres, said mainspring having a coating containing a thermoset or thermoplastic polymer. The mainspring proposed reduces the friction of the turns of the mainspring.