Barrier Coating Composition for Crack-Resistant Packaging

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Solution Overview

Problem

Conventional coatings for packaging materials fail to provide effective grease and water vapor barriers while resisting cracking, adhering to adjacent layers during processing, and ensuring recyclability, especially for foodstuff and consumable liquids packaging.

Innovation Solution

A barrier coating composition comprising 30-70 weight-% of styrene (meth)acrylate copolymer with a glass transition temperature ≤20°C, 30-70 weight-% of polyvinyl alcohol, and up to 5.0 weight-% of a cross-linker, applied on a substrate with lignocellulosic fibers, which maintains barrier properties and prevents cracking during creasing and folding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional fluorochemicals are used in coating compositions to provide desired barrier properties with resistance to cracking, then grease and water vapour barrier properties are improved, but environmental compatibility deteriorates

Engineering Contradiction:
Improvebarrier propertiesVSAvoidenvironmental compatibility
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by replacing fluorochemicals with a specific polymer combination (styrene-methacrylate copolymer with Tg ≤20°C and polyvinyl alcohol) that achieves comparable barrier properties without the environmental harm of conventional fluorochemicals

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite coating system combining styrene-methacrylate copolymer and polyvinyl alcohol in specific ratios (30-70 wt% each) to achieve the desired barrier properties as an alternative to single-component fluorochemical coatings

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If the coating layer softens under high pressure and high temperature during manufacturing, then ease of operation improves, but blocking occurs and productivity deteriorates

Engineering Contradiction:
Improvecoating applicationVSAvoidmanufacturing speed
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The patent optimizes the glass transition temperature parameter of the copolymer (Tg ≤20°C) to achieve the right balance: soft enough for easy coating application but stable enough to prevent blocking during high-speed manufacturing and converting processes

Inventive Principle:
Principle #35Parameter changes

3Reliability

If traditional plastic films are laminated on the surface of paper or board to provide barrier properties, then grease and water vapour barrier properties are improved, but recyclability deteriorates

Engineering Contradiction:
Improvebarrier propertiesVSAvoidrecyclability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the material state from laminated plastic films to a polymer-based coating that can be applied directly to the paper or board surface, maintaining barrier properties while enabling recycling through repulping processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention extracts the barrier function from separate laminated plastic films and integrates it into a coating that is chemically compatible with the paper or board substrate, allowing the entire structure to be recycled together

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating composition provides excellent resistance to cracking, maintains barrier properties when folded, and supports recyclability, ensuring optimal performance for packaging applications while minimizing environmental impact.

Implementation Method 1

styrene (meth)acrylate copolymer, which is polymerised in the presence of a stabiliser, and which has a glass transition temperature Tg≤20° C.

Methodology Applied
Scientific EffectGlass transition:

Implementation Method 2

provide excellent grease and water vapour barrier properties

Methodology Applied
Scientific EffectBarrier properties:

Implementation Method 3

at the most 5.0 weight-% of a cross-linker, which reacts with —OH or —COOH groups

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Data Source

PatentUS11525218B2Barrier coating composition, sheet-like product and its use
Publication Date: 2022.12.13 KEMIRA OY
  • US11525218B2 patent drawing
  • US11525218B2 patent drawing
  • US11525218B2 patent drawing

AI summary

A barrier coating composition is disclosed including 30-70 weight-% of a styrene (meth)acrylate copolymer, polymerised in the presence of a stabiliser, and the styrene (meth)acrylate copolymer having a glass transition temperature Tg≤20° C., preferably ≤10° C., 30-70 weight-% of a polyvinyl alcohol, and at most 5.0 weight-% of a cross-linker, reacting with —OH or —COOH groups. Further disclosed is a sheet-like product coated with the coating composition.