Barrier Film MFC Layer PHA Primer Aluminum Oxide Delamination

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Solution Overview

Problem

Existing packaging materials face issues with delamination due to moisture and environmental contamination from metallization layers, hindering recyclability and sustainability.

Innovation Solution

A barrier film comprising a microfibrillated cellulose (MFC) layer with a PHA primer and a thin vacuum-deposited layer, such as aluminum oxide, providing improved barrier properties and recyclability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If PVOH is used as pre-coating or tie layer, then adhesion is improved, but delamination risk increases under high humidity or moisture diffusion conditions

Engineering Contradiction:
ImproveadhesionVSAvoiddelamination resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent introduces an intermediary layer between the PVOH tie layer and the metallization layer to prevent direct contact and potential delamination. This intermediary acts as a buffer that maintains adhesion while protecting against moisture-induced dissolution of PVOH, thereby resolving the contradiction between achieving strong adhesion and preventing delamination under humid conditions.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs a sacrificial or replaceable intermediate layer that can be easily removed or replaced if delamination occurs. This layer serves as a temporary protective measure that sacrifices itself to prevent failure of the entire packaging structure, allowing the main functional layers to remain intact.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If metallization layer is used, then barrier properties are improved, but environmental contamination increases due to metal leaching

Engineering Contradiction:
Improvebarrier propertiesVSAvoidenvironmental contamination
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent introduces an intermediary barrier layer between the metallization layer and the external environment. This intermediary layer maintains the excellent barrier properties of the metallization against gases and moisture while preventing direct contact between metals and soil, thereby blocking the leaching pathway and eliminating environmental contamination.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent extracts or removes the metallization layer from direct contact with the environment by placing it within the multi-layer structure where it is isolated from external exposure. The functional barrier properties are retained through the layered construction, while the harmful metal leaching is eliminated by taking out the metallization from the harmful environmental interface.

Inventive Principle:
Principle #2Taking out (Extraction)

3Object-affected harmful factors

If aluminium foil is used, then barrier properties against aroma, light, water vapor and gases are improved, but recyclability and sustainability worsen

Engineering Contradiction:
Improvebarrier propertiesVSAvoidrecyclability
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent segments the packaging structure into distinct functional layers, with the metallization or barrier layer separated from the recyclable paperboard substrate by intermediate and protective layers. This segmentation allows the barrier function to be maintained while enabling the paper-based components to be easily separated and recycled independently, resolving the contradiction between achieving superior barrier properties and maintaining recyclability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent designs the packaging structure so that non-recyclable or difficult-to-recycle components (such as metallization layers or plastic coatings) can be easily discarded or removed, while the valuable recyclable paperboard substrate is recovered and reused. This approach maintains the necessary barrier properties through the discarded layers while maximizing the recovery and reuse of sustainable materials.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The film offers enhanced barrier performance against gases and moisture, is recyclable, and reduces environmental contamination, while maintaining mechanical strength and reusability.

Implementation Method 1

a thin vacuum deposited layer coated on a first primer layer which vacuum deposited layer has a thickness of 20-500 nm

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS20250206509A1A barrier film for a packaging material and a packaging material
Publication Date: 2025.06.26 STORA ENSO OYJ
  • US20250206509A1 patent drawing
  • US20250206509A1 patent drawing
  • US20250206509A1 patent drawing

AI summary

A barrier film (1) for a paper or paperboard-based packaging material, said barrier film comprising a, MFC layer, (2) with a grammage in the range 20-100 g/m2, and a density higher than 650 kg/m3. The barrier film further comprises a PHA, dispersion coated, primer layer (3, 9) coated on at least one side of the MFC layer, wherein the primer layer has a coating weight 0.5-12 g/m2; the primer layer (3, 9) comprises a PHA type selected from the group consisting of PHB, PHBV, PHBH, P(3HB4HB), other co-polymers of PHB, other homopolymers such as PHO, PHH, P3HP, and combinations thereof; and a thin vacuum deposited layer (4) coated on a first primer layer (3) which vacuum deposited layer has a thickness of 20-500 nm, the vacuum deposited layer comprises material selected from the group consisting of aluminum, magnesium, silicon, copper, aluminum oxides, magnesium oxides, silicon oxides and combinations thereof, preferably aluminum oxides.