Barrier Film Optical Stack for Stable Quantum Dot Color Output

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Solution Overview

Problem

The instability of quantum dots in liquid crystal display devices due to moisture and oxygen exposure leads to changes in color over time, affecting the color purity and quality of the display.

Innovation Solution

A barrier film comprising specific refractive index relationships and thicknesses of inorganic oxide and organic coating layers, which suppresses color changes by controlling the spectral transmission spectrum.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a quantum dot-containing layer is protected by a barrier film with base material, inorganic oxide layer, and organic coating layer, then the quantum dot is protected from moisture and oxygen, but the color stability deteriorates due to organic coating layer swelling in high humidity

Engineering Contradiction:
Improveprotection from moisture and oxygenVSAvoidcolor stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by precisely controlling the thickness of the organic coating layer (70-480 nm) and the optical path difference (within ±10 nm of integer multiples of 112.5 nm). This quantitative parameter optimization ensures that even when the organic coating layer swells in high humidity, the optical interference conditions remain stable, maintaining color consistency while preserving moisture and oxygen protection functionality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite barrier film structure combining inorganic oxide layers (providing barrier function) with organic coating layers (controlling optical properties). The inorganic oxide layers block moisture and oxygen, while the organic coating layers with specific thickness control light interference, creating a multi-functional composite that simultaneously achieves protection and color stability.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the organic coating layer thickness is increased to improve barrier performance, then protection from moisture and oxygen is improved, but color stability deteriorates due to swelling-induced spectral shifts

Engineering Contradiction:
Improvebarrier performanceVSAvoidspectral transmission stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent optimizes the thickness parameter of the organic coating layer within the specific range of 70-480 nm and controls the optical path difference to be within ±10 nm of integer multiples of 112.5 nm. This precise parameter control allows the organic coating layer to provide adequate barrier performance while minimizing swelling-induced spectral shifts, as the optimized thickness creates stable optical interference conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies partial action by using a moderate organic coating layer thickness (70-480 nm) that provides sufficient barrier performance without excessive thickness that would cause problematic swelling. This optimized thickness is enough to provide protection but not so thick as to cause severe color instability, achieving a balance between the two requirements.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The barrier film effectively stabilizes the color output of liquid crystal displays by minimizing changes in the balance of light transmission through the wavelength conversion sheet, maintaining color purity over time.

Implementation Method 1

refractive indexes of the light-transmitting base material, the inorganic oxide layer A, the organic coating layer B, the inorganic oxide layer C, and the organic coating layer D are defined as n0, nA, nB, nC, and nD, respectively, thicknesses of the light-transmitting base material, the inorganic oxide layer A, the organic coating layer B, the inorganic oxide layer C, and the organic coating layer D are defined as t0, tA, tB, tC, and tD, respectively

Methodology Applied
Scientific EffectOptical interference: Interference

Implementation Method 2

a reflectance at an interface between the inorganic oxide layer A and the organic coating layer B is larger than a reflectance at an interface between the light-transmitting base material and the inorganic oxide layer A

Methodology Applied
Scientific EffectLight reflection: Reflection

Data Source

PatentUS12496802B2Barrier film, wavelength conversion sheet using same, backlight and liquid crystal display device
Publication Date: 2025.12.16 DAI NIPPON PRINTING CO LTD
  • US12496802B2 patent drawing
  • US12496802B2 patent drawing
  • US12496802B2 patent drawing

AI summary

Provided is a barrier film that can suppress a change in color when applied to a wavelength conversion sheet. A barrier film for a wavelength conversion sheet, comprising an inorganic oxide layer A, an organic coating layer B, an inorganic oxide layer C, and an organic coating layer D in presented order on a light-transmitting base material; wherein refractive indexes of the inorganic oxide layer A, the organic coating layer B, the inorganic oxide layer C, and the organic coating layer D are defined as nA, nB, nC, and nD, respectively; thicknesses of the organic coating layer B and the organic coating layer D are defined as tB and tD, respectively; nA and nC are larger than nB and nD; and d1 represented by the following expression 1 represents a range of x±0.10 wherein x is an integer of 2 to 13.d1=nB×tB/112.5 nm+nD×tD/112.5 nm  (Expression 1)