Barrier Filter for Oxygenate Catalyst Regeneration

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Solution Overview

Problem

The existing processes for converting oxygenates to olefins face challenges such as catalyst deactivation due to coke deposition, particulate emissions in flue gas, and potential catalyst loss, necessitating improved methods for catalyst regeneration and particulate removal.

Innovation Solution

A method involving the regeneration of spent catalyst, followed by treatment with a barrier filter to separate catalyst particles from the flue gas, and subsequent return of filtered catalyst particles to the reactor, along with a system incorporating a regenerator and a barrier filter to enhance catalyst utilization and containment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If spent catalyst is regenerated by combustion with oxygen-containing air in a regenerator, then catalytic activity is restored, but particulate emissions and catalyst loss occur

Engineering Contradiction:
Improvecatalytic activityVSAvoidparticulate emissions
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

A filter is introduced as an intermediary component between the regenerator combustion chamber and the atmosphere. This filter captures particulate matter from the flue gas stream, allowing the regenerator to maintain its combustion function while preventing harmful particulate emissions from being released into the environment.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The particulate matter that would normally be harmful emissions is instead captured and converted into recoverable catalyst material. The filter transforms what was previously waste (particulate emissions) into a valuable resource (recyclable catalyst), thereby converting harm into benefit.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Object-generated harmful factors

If barrier filter is added to remove catalyst particles from flue gas, then particulate removal is achieved, but device complexity increases

Engineering Contradiction:
Improveparticulate removalVSAvoidsystem complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The filtration function is extracted as a separate, standalone component from the regenerator system. This modular approach allows the filter to be independently selected, installed, and maintained without redesigning the entire regenerator, thereby managing complexity through functional decomposition.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The filter is designed to capture and hold particulate matter for subsequent recovery and recycling. Rather than simply eliminating particles, the system recovers the catalyst material contained in the particles, transforming a potential waste stream into a valuable resource that can be returned to the reactor.

Inventive Principle:
Principle #34Discarding and recovering

3Quantity of substance

If catalyst particles are separated and returned to reactor, then catalyst utilization is maximized, but loss of time in separation and return process occurs

Engineering Contradiction:
Improvecatalyst utilizationVSAvoidprocessing time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The filter is integrated into the continuous flue gas flow path, allowing catalyst particle capture to occur continuously without interrupting the regenerator operation. The captured particles are held in the filter for later recovery, maintaining continuous useful action while enabling catalyst utilization maximization.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach maximizes catalyst utilization, achieves complete particulate removal from the flue gas, and provides protection against catalyst loss, ensuring efficient conversion of oxygenates to olefins while simplifying the regenerator cyclone design and operation.

Implementation Method 1

The flue gas containing catalyst particles is then treated with a barrier filter to separate catalyst particles from the flue gas.

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Implementation Method 2

During such regeneration processing, the spent catalyst is commonly directed to the regenerator where combustion with oxygen-containing air burns coke deposits from the catalyst material.

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS7439414B2Oxygenate conversion catalyst processing
Publication Date: 2008.10.21 UOP LLC
  • US7439414B2 patent drawing
  • US7439414B2 patent drawing
  • US7439414B2 patent drawing

AI summary

Improved processing of spent catalyst from an oxygenate-containing feedstock to olefins conversion process is realized through the employment of a barrier filter to treat a catalyst particle-containing flue gas resulting from a catalyst regenerator. The barrier filter serves to separate the catalyst particles from the flue gas. Catalyst material so recovered can, with or without classifying, subsequently be appropriately recycled and further used.